10.1107/s0909049500020896
Crossref journal-article
International Union of Crystallography (IUCr)
Journal of Synchrotron Radiation (329)
Abstract

The local structures of three phases; stable compound Sb2Te3, metastable crystalline c-SbTe and amorphous a-SbTe films having the atomic ratio Sb/Te=3; in Sb-Te system have been studied by EXAFS. The c-SbTe has a partly similar local structure to crystalline Sb2Te3. The a-SbTe film has a local structure of NaCl-type, which is topologically analogous to the crystalline form. The amorphous phase has shorter bond distances 2.86 Å (around Sb-site) and 2.83 Å (around Te-site) than the corresponding distances 2.89 Å and 2.87 Å in the crystalline phase. This unbalanced bond distances between the Sb-site and Te-site implies that site-disordering occurs. Shortening of bond distances in the amorphous phase is due to the relaxation of locally distorted crystalline structure.

Bibliography

Tani, K., Yiwata, N., Harigaya, M., Emura, S., & Nakata, Y. (2001). EXAFS study of Sb–Te alloy films. Journal of Synchrotron Radiation, 8(2), 749–751.

Authors 5
  1. Katsuhiko Tani (first)
  2. Noriyuki Yiwata (additional)
  3. Makoto Harigaya (additional)
  4. Shuichi Emura (additional)
  5. Yoshiyuki Nakata (additional)
References 0 Referenced 11

None

Dates
Type When
Created 23 years ago (July 27, 2002, 2:04 a.m.)
Deposited 7 months, 1 week ago (Jan. 10, 2025, 8:40 a.m.)
Indexed 7 months, 1 week ago (Jan. 11, 2025, 12:29 a.m.)
Issued 24 years, 5 months ago (March 1, 2001)
Published 24 years, 5 months ago (March 1, 2001)
Published Online 24 years, 5 months ago (March 1, 2001)
Published Print 24 years, 5 months ago (March 1, 2001)
Funders 0

None

@article{Tani_2001, title={EXAFS study of Sb–Te alloy films}, volume={8}, ISSN={0909-0495}, url={http://dx.doi.org/10.1107/s0909049500020896}, DOI={10.1107/s0909049500020896}, number={2}, journal={Journal of Synchrotron Radiation}, publisher={International Union of Crystallography (IUCr)}, author={Tani, Katsuhiko and Yiwata, Noriyuki and Harigaya, Makoto and Emura, Shuichi and Nakata, Yoshiyuki}, year={2001}, month=mar, pages={749–751} }