DOI: 10.1098/rspa.1984.0055. Review Lecture - Fast ionic conduction in solid

Review Lecture - Fast ionic conduction in solid

10.1098/rspa.1984.0055

Crossref journal-article

The Royal Society

Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences (175)

Abstract

Four classes of solid ionic conductors may be distinguished: (a) ion exchangers, (b) electrolytes, (c) electrodes, and (d) chemical stores. Each has important applications with different fabrication requirements. Fast ion transport is required in electric-power applications, and various strategies are discussed for power batteries. The design of new materials begins with a theoretical model for ionic transport; the situation in stoichiometric compounds is compared with that in doped compounds, and electrolytes are contrasted with mixed ionic-electronic conductors. The most significant parameters for the synthetic chemist are the factors that govern the activation enthalpy ∆Hmfor diffusion, the concentrationcof mobile carriers, and the temperatureTtfor any phase transition from a normal to a fast ionic conductor. Strategies for decreasing ∆Hmand increasingcprove to be ion-specific, and the most successful strategies for each mobile ion are presented. The origin of aTtin stoichiometric compounds and the distinction between smooth and first-order transitions are also considered.

Bibliography

Review Lecture - Fast ionic conduction in solid. (1984). Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences, 393(1805), 215â234.

Authors 0

None

References 13 Referenced 65

10.1103/PhysRevB.23.2876
G oodenough J . B . H ong H . Y .-P . & K afalas J . A. 1976 M ater. Res. B ull. 11 203-223. (10.1007/BF01580390)
G oodenough J . B. 1978 I n Solid electrolytes (ed. P . H agenm uller & W . V an Gool) chap. 23. N .Y .: A cadem ic Press.
M izushim a K . Jon es P . C. W isem an P . J . & G oodenough J . B. 1980 M ater. Res. B ull. 15 783-789. (10.1016/0025-5408(80)90012-4)
R a b en au A. 1978 A d v . solid S t. P h ys. 18 77-108.
Salam on M. B. (ed.) 1979 P hysics of superionic conductors. B erlin: Springer-V erlag.
Schulz H . 1982 In Proc. 2nd European Conference on Solid State Chemistry Eindhoven University of Technology 7-9 Ju n e . Stud inorg. Chem. 3.
Schulz H . & T hiem ann K . H . 1979 A cta crystaA 35 309-314. (10.1107/S0567739479000632)
T hackeray M. M. D avid W . I. F . B ruce P . G. & G oodenough J . B. 1983 M ater. Res. B ull. 18 461-472. (10.1016/0025-5408(83)90138-1)
T hackeray M. M. D avid W . I. F . & G oodenough J . B. 1982 M ater. Res. B ull. 17 785-793.
{'key': 'p_11', 'first-page': '621', 'article-title': 'A p p l. P hys', 'volume': '30', 'author': 'von Alpen U .', 'year': '1977', 'journal-title': 'Lett.'} / Lett. / A p p l. P hys by von Alpen U . (1977)
W eber N. & K um m er J. T . 1967 I n Proc. 21 A n n . Power Sources Conf. pp. 37-39. F o rt M onm outh N. J . : Pow er Sources Division U .S. A rm y Signal R esearch and D evelopm ent L ab o rato ry .
{'key': 'p_13', 'first-page': '315', 'article-title': 'J . electrochem', 'volume': '123', 'year': '1976', 'journal-title': 'Soc.'} / Soc. / J . electrochem (1976)

Dates

Type	When
Created	18 years, 8 months ago (Dec. 15, 2006, 5:20 p.m.)
Deposited	2 years, 3 months ago (May 9, 2023, 9:09 p.m.)
Indexed	1 month, 1 week ago (July 11, 2025, 6:38 a.m.)
Issued	41 years, 2 months ago (June 8, 1984)
Published	41 years, 2 months ago (June 8, 1984)
Published Online	28 years, 7 months ago (Jan. 1, 1997)
Published Print	41 years, 2 months ago (June 8, 1984)

Funders 0

None

BibTeX

@article{1984, volume={393}, ISSN={0080-4630}, url={http://dx.doi.org/10.1098/rspa.1984.0055}, DOI={10.1098/rspa.1984.0055}, number={1805}, journal={Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences}, publisher={The Royal Society}, year={1984}, month=jun, pages={215–234} }

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