DOI: 10.1073/pnas.97.11.5704. A route to hierarchical materials based on complexes of metallosupramolecular polyelectrolytes and amphiphiles

A route to hierarchical materials based on complexes of metallosupramolecular polyelectrolytes and amphiphiles

10.1073/pnas.97.11.5704

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Anisotropic thin film materials of metallosupramolecular polyelectrolyte–amphiphile complexes (denoted PACs) with structures at several length scales were fabricated through a multistep self-assembly process. Metal ion-mediated self-assembly of the ditopic ligand 1,4-bis(2,2′:6′,2′′-terpyridine-4′-yl)benzene and electrostatic binding with the amphiphile dihexadecyl phosphate result in a PAC with tailored surface chemical properties, including solubility and surface activity. The PAC forms a stable monolayer at the air–water interface that is readily transferred and oriented on solid supports with the Langmuir–Blodgett technique. The presented strategy unifies colloid and metallosupramolecular chemistry and opens a versatile route to hierarchical materials with tailored structures and functions.

Bibliography

Kurth, D. G., Lehmann, P., & SchÃ¼tte, M. (2000). A route to hierarchical materials based on complexes of metallosupramolecular polyelectrolytes and amphiphiles. Proceedings of the National Academy of Sciences, 97(11), 5704â5707.

Authors 3

Dirk G. Kurth (first)
Pit Lehmann (additional)
Markus Schütte (additional)

References 24 Referenced 107

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:38 a.m.)
Deposited	1 year, 7 months ago (Jan. 3, 2024, 11:55 p.m.)
Indexed	1 year, 2 months ago (June 18, 2024, 7:32 p.m.)
Issued	25 years, 3 months ago (May 23, 2000)
Published	25 years, 3 months ago (May 23, 2000)
Published Online	25 years, 3 months ago (May 23, 2000)
Published Print	25 years, 3 months ago (May 23, 2000)

Funders 0

None

BibTeX

@article{Kurth_2000, title={A route to hierarchical materials based on complexes of metallosupramolecular polyelectrolytes and amphiphiles}, volume={97}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.97.11.5704}, DOI={10.1073/pnas.97.11.5704}, number={11}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Kurth, Dirk G. and Lehmann, Pit and Schütte, Markus}, year={2000}, month=may, pages={5704–5707} }

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