DOI: 10.1073/pnas.80.24.7684. Systematic variation of metal—metal bond order in metalloporphyrin dimers

Systematic variation of metal—metal bond order in metalloporphyrin dimers

10.1073/pnas.80.24.7684

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

A general method for synthesizing a novel class of metalloporphyrin dimers containing unbridged metal—metal bonds is presented. By choosing the appropriate metal, the bond order in these dimers can be varied systematically. The synthesis and characterization of osmium(II) and molybdenum(II) porphyrin dimers containing the respective metal—metal double and quadruple bonds are described. A simple molecular orbital treatment that accounts for the metal—metal bonding, spin state, and geometry in these complexes is discussed.

Bibliography

Collman, J. P., Barnes, C. E., & Woo, L. K. (1983). Systematic variation of metalâmetal bond order in metalloporphyrin dimers. Proceedings of the National Academy of Sciences, 80(24), 7684â7688.

Authors 3

James P. Collman (first)
Craig E. Barnes (additional)
L. Keith Woo (additional)

References 0 Referenced 42

None

Dates

Type	When
Created	19 years, 2 months ago (May 31, 2006, 5:18 a.m.)
Deposited	3 years, 4 months ago (April 13, 2022, 11:58 a.m.)
Indexed	1 year, 5 months ago (March 20, 2024, 5:45 a.m.)
Issued	41 years, 8 months ago (Dec. 1, 1983)
Published	41 years, 8 months ago (Dec. 1, 1983)
Published Online	41 years, 8 months ago (Dec. 1, 1983)
Published Print	41 years, 8 months ago (Dec. 1, 1983)

Funders 0

None

BibTeX

@article{Collman_1983, title={Systematic variation of metal—metal bond order in metalloporphyrin dimers}, volume={80}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.80.24.7684}, DOI={10.1073/pnas.80.24.7684}, number={24}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Collman, James P. and Barnes, Craig E. and Woo, L. Keith}, year={1983}, month=dec, pages={7684–7688} }

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