DOI: 10.1073/pnas.77.10.5583. Microwave spectrum and molecular structure of the carbon monoxide-hydrogen bromide molecular complex

Microwave spectrum and molecular structure of the carbon monoxide-hydrogen bromide molecular complex

10.1073/pnas.77.10.5583

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Rotational spectra have been assigned for five isotopic species of the OC···HBr hydrogen-bonded molecular complex by using pulsed microwave Fourier transform spectroscopy in a Fabry-Perot cavity and a pulsed supersonic nozzle as the molecular source. The rotational constants, centrifugal distortion constants, Br nuclear-quadrupole-coupling constants, and Br spin-rotation constants were determined and from them, the vibrationally averaged structure of OCHBr was derived. This structure is consistent with a linear geometry at equilibrium and an atomic arrangement as written above. The intermolecular potential binding CO to HBr is discussed.

Authors 5

M. R. Keenan (first)
T. K. Minton (additional)
A. C. Legon (additional)
T. J. Balle (additional)
W. H. Flygare (additional)

References 0 Referenced 52

None

Dates

Type	When
Created	19 years, 2 months ago (May 31, 2006, 4:06 a.m.)
Deposited	3 years, 4 months ago (April 13, 2022, 11:25 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 7:26 a.m.)
Issued	44 years, 10 months ago (Oct. 1, 1980)
Published	44 years, 10 months ago (Oct. 1, 1980)
Published Online	44 years, 10 months ago (Oct. 1, 1980)
Published Print	44 years, 10 months ago (Oct. 1, 1980)

Funders 0

None

BibTeX

@article{Keenan_1980, title={Microwave spectrum and molecular structure of the carbon monoxide-hydrogen bromide molecular complex}, volume={77}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.77.10.5583}, DOI={10.1073/pnas.77.10.5583}, number={10}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Keenan, M. R. and Minton, T. K. and Legon, A. C. and Balle, T. J. and Flygare, W. H.}, year={1980}, month=oct, pages={5583–5587} }

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