DOI: 10.1073/pnas.1934837100. Dewetting-induced collapse of hydrophobic particles

Dewetting-induced collapse of hydrophobic particles

10.1073/pnas.1934837100

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

A molecular dynamics study of the depletion of water (drying) around a single and between two hydrophobic nanoscale oblate plates in explicit water as a function of the distance of separation between them, their size, and the strength of the attraction between the plates and the water molecules is presented. A simple macroscopic thermodynamic model based on Young's law successfully predicts drying between the stacked plates and accounts for the free-energy barriers to this drying. However, because drying around a single plate is not macroscopic, a molecular theory is required to describe it. The data are consistent with the rate-determining step in the hydrophobic collapse of the two plates being a large-scale drying fluctuation, characterized by a free-energy barrier that grows with particle size.

Bibliography

Huang, X., Margulis, C. J., & Berne, B. J. (2003). Dewetting-induced collapse of hydrophobic particles. Proceedings of the National Academy of Sciences, 100(21), 11953â11958.

Authors 3

X. Huang (first)
C. J. Margulis (additional)
B. J. Berne (additional)

References 52 Referenced 255

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Dates

Type	When
Created	21 years, 10 months ago (Oct. 14, 2003, 3:05 p.m.)
Deposited	3 years, 4 months ago (April 13, 2022, 6:24 a.m.)
Indexed	2 months, 2 weeks ago (June 5, 2025, 7:24 p.m.)
Issued	21 years, 10 months ago (Sept. 24, 2003)
Published	21 years, 10 months ago (Sept. 24, 2003)
Published Online	21 years, 10 months ago (Sept. 24, 2003)
Published Print	21 years, 10 months ago (Oct. 14, 2003)

Funders 0

None

BibTeX

@article{Huang_2003, title={Dewetting-induced collapse of hydrophobic particles}, volume={100}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.1934837100}, DOI={10.1073/pnas.1934837100}, number={21}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Huang, X. and Margulis, C. J. and Berne, B. J.}, year={2003}, month=sep, pages={11953–11958} }

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