DOI: 10.1073/pnas.190325397. Nanoscale imaging of chemical interactions: Fluorine on graphite

Nanoscale imaging of chemical interactions: Fluorine on graphite

10.1073/pnas.190325397

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Using C 60 -functionalized scanning tunneling microscope tips, we have investigated the adsorption of fluorine on graphite. Based on characteristics of the accompanying electron standing waves, we are able to distinguish the fluorine adatoms that have bonded ionically to the graphite surface from those that have formed covalent bonds with the surface. This result permits determination of the ratio of ionic to covalent C–F bonds on graphite obtained by gas phase fluorination, which seems to be temperatureindependent between 200 and 300°C under the reaction conditions used.

Bibliography

Kelly, K. F., Mickelson, E. T., Hauge, R. H., Margrave, J. L., & Halas, N. J. (2000). Nanoscale imaging of chemical interactions: Fluorine on graphite. Proceedings of the National Academy of Sciences, 97(19), 10318â10321.

Authors 5

Kevin F. Kelly (first)
Edward T. Mickelson (additional)
Robert H. Hauge (additional)
John L. Margrave (additional)
Naomi J. Halas (additional)

References 33 Referenced 29

10.1039/DT9740001268
10.1021/ar50128a002
10.1002/anie.199713401
M S Dresselhaus, M Endo, J-P Issi Fluorine-Carbon and Fluoride-Carbon Materials, ed T Nakajima (Marcel-Dekker, New York), pp. 95 (1995). / Fluorine-Carbon and Fluoride-Carbon Materials by Dresselhaus M S (1995)
10.1103/PhysRevLett.71.1071
10.1038/363524a0
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10.1126/science.274.5284.118
10.1103/PhysRevLett.76.2298
10.1103/PhysRevLett.76.1075
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10.1103/PhysRevB.31.805
10.1103/PhysRevLett.50.1998
10.1103/PhysRevB.58.13931
T Mallouk, N Bartlett Chem. Commun., 103–105. (1983). / Chem. Commun. by Mallouk T (1983)
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 10:31 a.m.)
Deposited	3 years, 4 months ago (April 13, 2022, 4:47 a.m.)
Indexed	1 year ago (Aug. 12, 2024, 12:34 p.m.)
Issued	25 years ago (Aug. 29, 2000)
Published	25 years ago (Aug. 29, 2000)
Published Online	25 years ago (Aug. 29, 2000)
Published Print	24 years, 11 months ago (Sept. 12, 2000)

Funders 0

None

BibTeX

@article{Kelly_2000, title={Nanoscale imaging of chemical interactions: Fluorine on graphite}, volume={97}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.190325397}, DOI={10.1073/pnas.190325397}, number={19}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Kelly, Kevin F. and Mickelson, Edward T. and Hauge, Robert H. and Margrave, John L. and Halas, Naomi J.}, year={2000}, month=aug, pages={10318–10321} }

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