DOI: 10.1073/pnas.1700103114. Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-man’s land

Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-man’s land

10.1073/pnas.1700103114

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

We review the recent research on supercooled and glassy water, focusing on the possible origins of its complex behavior. We stress the central role played by the strong directionality of the water–water interaction and by the competition between local energy, local entropy, and local density. In this context we discuss the phenomenon of polyamorphism (i.e., the existence of more than one disordered solid state), emphasizing both the role of the preparation protocols and the transformation between the different disordered ices. Finally, we present the ongoing debate on the possibility of linking polyamorphism with a liquid–liquid transition that could take place in the no-man’s land, the temperature–pressure window in which homogeneous nucleation prevents the investigation of water in its metastable liquid form.

Bibliography

Handle, P. H., Loerting, T., & Sciortino, F. (2017). Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-manâs land. Proceedings of the National Academy of Sciences, 114(51), 13336â13344.

Authors 3

Philip H. Handle (first)
Thomas Loerting (additional)
Francesco Sciortino (additional)

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Dates

Type	When
Created	7 years, 9 months ago (Nov. 13, 2017, 2:50 p.m.)
Deposited	3 years, 4 months ago (April 13, 2022, 3:05 a.m.)
Indexed	2 weeks ago (Aug. 6, 2025, 8:27 a.m.)
Issued	7 years, 9 months ago (Nov. 13, 2017)
Published	7 years, 9 months ago (Nov. 13, 2017)
Published Online	7 years, 9 months ago (Nov. 13, 2017)
Published Print	7 years, 8 months ago (Dec. 19, 2017)

Funders 0

None

BibTeX

@article{Handle_2017, title={Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-man’s land}, volume={114}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.1700103114}, DOI={10.1073/pnas.1700103114}, number={51}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Handle, Philip H. and Loerting, Thomas and Sciortino, Francesco}, year={2017}, month=nov, pages={13336–13344} }

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