Abstract
The floating water bridge phenomenon is a freestanding rope-shaped connection of pure liquid water, formed under the influence of a high potential difference (approximately 15 kV). Several recent spectroscopic, optical, and neutron scattering studies have suggested that the origin of the bridge is associated with the formation of anisotropic chains of water molecules in the liquid. In this work, high energy X-ray diffraction experiments have been performed on a series of floating water bridges as a function of applied voltage, bridge length, and position within the bridge. The two-dimensional X-ray scattering data showed no direction-dependence, indicating that the bulk water molecules do not exhibit any significant preferred orientation along the electric field. The only structural changes observed were those due to heating, and these effects were found to be the same as for bulk water. These X-ray scattering measurements are supported by molecular dynamics (MD) simulations which were performed under electric fields of 10 6 V/m and 10 9 V/m. Directional structure factor calculations were made from these simulations parallel and perpendicular to the E-field. The 10 6 V/m model showed no significant directional-dependence (anisotropy) in the structure factors. The 10 9 V/m model however, contained molecules aligned by the E-field, and had significant structural anisotropy.
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Dates
Type | When |
---|---|
Created | 12 years, 10 months ago (Sept. 25, 2012, 6:48 a.m.) |
Deposited | 3 years, 4 months ago (April 15, 2022, 7:21 a.m.) |
Indexed | 3 weeks, 6 days ago (July 25, 2025, 6:26 a.m.) |
Issued | 12 years, 10 months ago (Sept. 24, 2012) |
Published | 12 years, 10 months ago (Sept. 24, 2012) |
Published Online | 12 years, 10 months ago (Sept. 24, 2012) |
Published Print | 12 years, 10 months ago (Oct. 9, 2012) |
@article{Skinner_2012, title={Structure of the floating water bridge and water in an electric field}, volume={109}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.1210732109}, DOI={10.1073/pnas.1210732109}, number={41}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Skinner, Lawrie B. and Benmore, Chris J. and Shyam, Badri and Weber, J. K. R. and Parise, John B.}, year={2012}, month=sep, pages={16463–16468} }