DOI: 10.1073/pnas.0804900105. Metal-organic frameworks with high capacity and selectivity for harmful gases

Metal-organic frameworks with high capacity and selectivity for harmful gases

10.1073/pnas.0804900105

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Benchmarks have been established for the performance of six metal-organic frameworks (MOFs) and isoreticular MOFs (IRMOFs, which have the same underlying topology as MOF-5), MOF-5, IRMOF-3, MOF-74, MOF-177, MOF-199, and IRMOF-62, as selective adsorbents for eight harmful gases: sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, and carbon monoxide. Kinetic breakthrough measurements are used to determine the calculated dynamic adsorption capacity of each “benchmark” MOF for each gas. The capacity of each MOF is compared to that of a sample of Calgon BPL activated carbon. We find that pore functionality plays a dominant role in determining the dynamic adsorption performance of MOFs. MOFs featuring reactive functionality outperform BPL carbon in all but one case and exhibit high dynamic adsorption capacities up to 35% by weight.

Bibliography

Britt, D., Tranchemontagne, D., & Yaghi, O. M. (2008). Metal-organic frameworks with high capacity and selectivity for harmful gases. Proceedings of the National Academy of Sciences, 105(33), 11623â11627.

Authors 3

David Britt (first)
David Tranchemontagne (additional)
Omar M. Yaghi (additional)

References 25 Referenced 866

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Dates

Type	When
Created	17 years ago (Aug. 18, 2008, 9:09 p.m.)
Deposited	3 years, 4 months ago (April 12, 2022, 5:22 p.m.)
Indexed	6 minutes ago (Aug. 29, 2025, 6:06 p.m.)
Issued	17 years ago (Aug. 19, 2008)
Published	17 years ago (Aug. 19, 2008)
Published Online	17 years ago (Aug. 19, 2008)
Published Print	17 years ago (Aug. 19, 2008)

Funders 0

None

BibTeX

@article{Britt_2008, title={Metal-organic frameworks with high capacity and selectivity for harmful gases}, volume={105}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.0804900105}, DOI={10.1073/pnas.0804900105}, number={33}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Britt, David and Tranchemontagne, David and Yaghi, Omar M.}, year={2008}, month=aug, pages={11623–11627} }

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