DOI: 10.1073/pnas.0602439103. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks

10.1073/pnas.0602439103

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Twelve zeolitic imidazolate frameworks (ZIFs; termed ZIF-1 to -12) have been synthesized as crystals by copolymerization of either Zn(II) (ZIF-1 to -4, -6 to -8, and -10 to -11) or Co(II) (ZIF-9 and -12) with imidazolate-type links. The ZIF crystal structures are based on the nets of seven distinct aluminosilicate zeolites: tetrahedral Si(Al) and the bridging O are replaced with transition metal ion and imidazolate link, respectively. In addition, one example of mixed-coordination imidazolate of Zn(II) and In(III) (ZIF-5) based on the garnet net is reported. Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity (Langmuir surface area = 1,810 m 2 /g), high thermal stability (up to 550°C), and remarkable chemical resistance to boiling alkaline water and organic solvents.

Bibliography

Park, K. S., Ni, Z., CÃ´tÃ©, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., OâKeeffe, M., & Yaghi, O. M. (2006). Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proceedings of the National Academy of Sciences, 103(27), 10186â10191.

Authors 9

Kyo Sung Park (first)
Zheng Ni (additional)
Adrien P. Côté (additional)
Jae Yong Choi (additional)
Rudan Huang (additional)
Fernando J. Uribe-Romo (additional)
Hee K. Chae (additional)
Michael O’Keeffe (additional)
Omar M. Yaghi (additional)

References 21 Referenced 6,628

T. L. M. Maesen, B. Marcus Introduction to Zeolite Science and Practice, eds H. van Bekkum, E. M. Flanigen, P. A. Jacobs, J. C. Jansen (Elsevier, Amsterdam), pp. 1–9 (2001). / Introduction to Zeolite Science and Practice by Maesen T. L. M. (2001)
C. Baerlocher, W. M. Meier, D. H. Olson Atlas of Zeolite Framework Types (Elsevier, 5th Ed, Amsterdam, 2001). / Atlas of Zeolite Framework Types by Baerlocher C. (2001)
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X.-C. Huang, J.-P. Zhang, X.-M. Chen Chin. Sci. Bull. 48, 1531–1534 (2003). / Chin. Sci. Bull. by Huang X.-C. (2003)
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D. W. Breck Zeolite Molecular Sieves (Wiley, New York), pp. 593–724 (1974). / Zeolite Molecular Sieves by Breck D. W. (1974)
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10.1021/cr60290a003

Dates

Type	When
Created	19 years, 2 months ago (June 23, 2006, 8:53 p.m.)
Deposited	3 years, 4 months ago (April 12, 2022, 3:22 p.m.)
Indexed	22 hours, 2 minutes ago (Aug. 31, 2025, 6:26 a.m.)
Issued	19 years, 1 month ago (July 5, 2006)
Published	19 years, 1 month ago (July 5, 2006)
Published Online	19 years, 1 month ago (July 5, 2006)
Published Print	19 years, 1 month ago (July 5, 2006)

Funders 0

None

BibTeX

@article{Park_2006, title={Exceptional chemical and thermal stability of zeolitic imidazolate frameworks}, volume={103}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.0602439103}, DOI={10.1073/pnas.0602439103}, number={27}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Park, Kyo Sung and Ni, Zheng and Côté, Adrien P. and Choi, Jae Yong and Huang, Rudan and Uribe-Romo, Fernando J. and Chae, Hee K. and O’Keeffe, Michael and Yaghi, Omar M.}, year={2006}, month=jul, pages={10186–10191} }

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