DOI: 10.1073/pnas.0408319102. Surface-enhanced Raman scattering on tunable plasmonic nanoparticle substrates

Surface-enhanced Raman scattering on tunable plasmonic nanoparticle substrates

10.1073/pnas.0408319102

Crossref journal-article

Proceedings of the National Academy of Sciences

Proceedings of the National Academy of Sciences (341)

Abstract

Au and Ag nanoshells are investigated as substrates for surface-enhanced Raman scattering (SERS). We find that SERS enhancements on nanoshell films are dramatically different from those observed on colloidal aggregates, specifically that the Raman enhancement follows the plasmon resonance of the individual nanoparticles. Comparative finite difference time domain calculations of fields at the surface of smooth and roughened nanoshells reveal that surface roughness contributes only slightly to the total enhancement. SERS enhancements as large as 2.5 × 10 10 on Ag nanoshell films for the nonresonant molecule p -mercaptoaniline are measured.

Bibliography

Jackson, J. B., & Halas, N. J. (2004). Surface-enhanced Raman scattering on tunable plasmonic nanoparticle substrates. Proceedings of the National Academy of Sciences, 101(52), 17930â17935.

Authors 2

J. B. Jackson (first)
N. J. Halas (additional)

References 41 Referenced 517

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Dates

Type	When
Created	20 years, 8 months ago (Dec. 17, 2004, 8:17 p.m.)
Deposited	3 years, 4 months ago (April 12, 2022, 10:17 a.m.)
Indexed	1 day, 10 hours ago (Aug. 23, 2025, 1 a.m.)
Issued	20 years, 8 months ago (Dec. 17, 2004)
Published	20 years, 8 months ago (Dec. 17, 2004)
Published Online	20 years, 8 months ago (Dec. 17, 2004)
Published Print	20 years, 7 months ago (Dec. 28, 2004)

Funders 0

None

BibTeX

@article{Jackson_2004, title={Surface-enhanced Raman scattering on tunable plasmonic nanoparticle substrates}, volume={101}, ISSN={1091-6490}, url={http://dx.doi.org/10.1073/pnas.0408319102}, DOI={10.1073/pnas.0408319102}, number={52}, journal={Proceedings of the National Academy of Sciences}, publisher={Proceedings of the National Academy of Sciences}, author={Jackson, J. B. and Halas, N. J.}, year={2004}, month=dec, pages={17930–17935} }

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