Abstract
Cyanohydrins, prepared in high optical purity from aryl aldehydes, have been converted into α- hydroxy aldehydes, β- hydroxy ketones and β- hydroxy amines without any racemization and frequently with good stereoselectivity for the erythro-diastereoisomer (>90%) at the newly introduced stereogenic centre.
Dates
Type | When |
---|---|
Created | 18 years, 8 months ago (Dec. 19, 2006, 7:47 p.m.) |
Deposited | 6 years, 9 months ago (Nov. 21, 2018, 2:09 a.m.) |
Indexed | 2 months ago (July 2, 2025, 1:30 p.m.) |
Issued | 35 years, 8 months ago (Jan. 1, 1990) |
Published | 35 years, 8 months ago (Jan. 1, 1990) |
Published Print | 35 years, 8 months ago (Jan. 1, 1990) |
@article{Jackson_1990, title={Applications of Optically Active Aryl Cyanohydrins in the Synthesis of α-Hydroxy Aldehydes, α-Hydroxy Ketones and β-Hydroxy Amines}, volume={43}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9902045}, DOI={10.1071/ch9902045}, number={12}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Jackson, WR and Jacobs, HA and Jayatilake, GS and Matthews, BR and Watson, KG}, year={1990}, pages={2045} }