DOI: 10.1071/ch9841405. Crystal structure of μ-Oxo-bis-fac-[triaqua-1,10-phenanthrolineiron(III)] Tetrakis(nitrate) monohydrate

Crystal structure of μ-Oxo-bis-fac-[triaqua-1,10-phenanthrolineiron(III)] Tetrakis(nitrate) monohydrate

10.1071/ch9841405

Crossref journal-article

CSIRO Publishing

Australian Journal of Chemistry (67)

Abstract

The crystal structure of the title compound, [(OH2)3(phen)FeOFe(phen)(OH2)3](NO3)4.(H2O)(phen = 1,10-phenanthroline), has been determined by single-crystal X-ray diffraction methods at 295 K, being refined by least-squares methods to a residual of 0.059 for 3467 independent 'observed'reflections. Crystals are monoclinic, P 21/c, a 18.202(6), b 9.771(4), c 19.459(7) �, β 94.46(3)�, Z = 4. Two of the four anions are disordered. Within the cation, the geometry is typical of high-spin iron(III). O(bridge)-Fe are 1.765(4), 1.784(4) �, with Fe-O-Fe 162.0(3)�. The three water molecules in the coordination sphere of each iron atom are fac; those trans to the O-Fe bond have long Fe-(OH2) distances [2.154(5), 2.125(5) �] compared to those trans to the phenanthroline chelates [2.028(5)-2.037(5) �]. Fe-N range from 2.143(6) to 2.166(6) �.

Bibliography

Healy, P., Patrick, J., & White, A. (1984). Crystal structure of Î¼-Oxo-bis-fac-[triaqua-1,10-phenanthrolineiron(III)] Tetrakis(nitrate) monohydrate. Australian Journal of Chemistry, 37(7), 1405.

Authors 3

PC Healy (first)
JM Patrick (additional)
AH White (additional)

References 0 Referenced 14

None

Dates

Type	When
Created	15 years ago (Sept. 1, 2010, 8:55 p.m.)
Deposited	6 years, 9 months ago (Nov. 20, 2018, 8:50 p.m.)
Indexed	1 year, 10 months ago (Oct. 10, 2023, 1:07 a.m.)
Issued	41 years, 8 months ago (Jan. 1, 1984)
Published	41 years, 8 months ago (Jan. 1, 1984)
Published Print	41 years, 8 months ago (Jan. 1, 1984)

Funders 0

None

BibTeX

@article{Healy_1984, title={Crystal structure of μ-Oxo-bis-fac-[triaqua-1,10-phenanthrolineiron(III)] Tetrakis(nitrate) monohydrate}, volume={37}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9841405}, DOI={10.1071/ch9841405}, number={7}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Healy, PC and Patrick, JM and White, AH}, year={1984}, pages={1405} }

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  "abstract": "<jats:p>The crystal structure of\nthe title compound, [(OH2)3(phen)FeOFe(phen)(OH2)3](NO3)4.(H2O)(phen\n= 1,10-phenanthroline), has been determined by single-crystal X-ray diffraction\nmethods at 295 K, being refined by\nleast-squares methods to a residual of 0.059 for 3467 independent 'observed'reflections. Crystals are monoclinic, P 21/c,\na 18.202(6), b 9.771(4), c 19.459(7) \ufffd,\n\u03b2 94.46(3)\ufffd, Z = 4. Two of the four anions are disordered. Within the\ncation, the geometry is typical of high-spin iron(III). O(bridge)-Fe are\n1.765(4), 1.784(4) \ufffd, with Fe-O-Fe 162.0(3)\ufffd. The three water molecules in the\ncoordination sphere of each iron atom are fac; those trans to the O-Fe bond have long Fe-(OH2) distances\n[2.154(5), 2.125(5) \ufffd] compared to those trans to the phenanthroline\nchelates [2.028(5)-2.037(5) \ufffd]. Fe-N range from\n2.143(6) to 2.166(6) \ufffd.</jats:p>",
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