DOI: 10.1071/ch9800949. Chemistry of the Group 1B metals. XIV. Some poly(pyrazolyl)borate derivatives containing gold

Chemistry of the Group 1B metals. XIV. Some poly(pyrazolyl)borate derivatives containing gold

10.1071/ch9800949

Crossref journal-article

CSIRO Publishing

Australian Journal of Chemistry (67)

Abstract

Reactions of poly(pyrazolyl)borate anions with HAuCl4 have given the complexes AuCl2[(pz)2BPh2], AuCl2[(pz)3BH], AuCl2[(Me2pz)3BH] and AuCl2[(pz)4B] (pz = pyrazolyl, C3H3N2; Me2pz = 3,5-dimethylpyrazolyl); AuCl2[(Me2pz)3BH] decomposes rather easily to form [AuCl2(Me2pz)]3, while Au(pz)[P(OMe)3] was obtained from a reaction between AuCl2[(pz)4B] and P(OMe)3.

Bibliography

Borkett, N., Bruce, M., & Walsh, J. (1980). Chemistry of the Group 1B metals. XIV. Some poly(pyrazolyl)borate derivatives containing gold. Australian Journal of Chemistry, 33(5), 949.

Authors 3

NF Borkett (first)
MI Bruce (additional)
JD Walsh (additional)

References 0 Referenced 10

None

Dates

Type	When
Created	14 years, 11 months ago (Sept. 1, 2010, 8:45 p.m.)
Deposited	6 years, 9 months ago (Nov. 20, 2018, 8:37 p.m.)
Indexed	2 years ago (Aug. 25, 2023, 7:30 a.m.)
Issued	45 years, 7 months ago (Jan. 1, 1980)
Published	45 years, 7 months ago (Jan. 1, 1980)
Published Print	45 years, 7 months ago (Jan. 1, 1980)

Funders 0

None

BibTeX

@article{Borkett_1980, title={Chemistry of the Group 1B metals. XIV. Some poly(pyrazolyl)borate derivatives containing gold}, volume={33}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9800949}, DOI={10.1071/ch9800949}, number={5}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Borkett, NF and Bruce, MI and Walsh, JD}, year={1980}, pages={949} }

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  "abstract": "<jats:p>Reactions of\npoly(pyrazolyl)borate anions with HAuCl4 have given the complexes\nAuCl2[(pz)2BPh2],\nAuCl2[(pz)3BH], AuCl2[(Me2pz)3BH]\nand AuCl2[(pz)4B] (pz = pyrazolyl, C3H3N2; Me2pz\n= 3,5-dimethylpyrazolyl); AuCl2[(Me2pz)3BH]\ndecomposes rather easily to form [AuCl2(Me2pz)]3,\nwhile Au(pz)[P(OMe)3]\nwas obtained from a reaction between AuCl2[(pz)4B]\nand P(OMe)3.</jats:p>",
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