DOI: 10.1071/ch9791613. Chemistry of the Group 1B Elements. XII. Some Poly(pyrazolyl)borate Complexes of Silver

Chemistry of the Group 1B Elements. XII. Some Poly(pyrazolyl)borate Complexes of Silver

10.1071/ch9791613

Crossref journal-article

CSIRO Publishing

Australian Journal of Chemistry (67)

Abstract

Reactions between silver(1) salts and poly(pyrazolyl)borate anions in the presence of donor ligands have given 21 complexes of general formula AgL(RnBH4-n) [L = PPh3, P(c6H4Me)3, P(OMe)3, P(OPh)3, AsPh3, SbPh3, o - C6H4( AsMe2)2 or ButNC; RnBH4-n = HB(pz)3, HB(Me2pz)3 orB(pz)4], and [Ag(HBR3)]2(dppe) (R = PZ or Me2pz) and {[Ag(HBR3)](dppm)}n (R = PZ, n = 1 ; R = Me2pz, n = 2). Their possible structures are discussed in the light of various spectroscopicdata obtained for them.

Bibliography

Salah, O., Ashby, G., Bruce, M., Pederzolli, E., & Walsh, J. (1979). Chemistry of the Group 1B Elements. XII. Some Poly(pyrazolyl)borate Complexes of Silver. Australian Journal of Chemistry, 32(7), 1613.

Authors 5

OMA Salah (first)
GS Ashby (additional)
MI Bruce (additional)
EA Pederzolli (additional)
JD Walsh (additional)

References 0 Referenced 20

None

Dates

Type	When
Created	15 years ago (Sept. 2, 2010, 12:37 a.m.)
Deposited	6 years, 9 months ago (Nov. 21, 2018, 1:35 a.m.)
Indexed	1 year, 10 months ago (Oct. 28, 2023, 12:43 a.m.)
Issued	46 years, 8 months ago (Jan. 1, 1979)
Published	46 years, 8 months ago (Jan. 1, 1979)
Published Print	46 years, 8 months ago (Jan. 1, 1979)

Funders 0

None

BibTeX

@article{Salah_1979, title={Chemistry of the Group 1B Elements. XII. Some Poly(pyrazolyl)borate Complexes of Silver}, volume={32}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9791613}, DOI={10.1071/ch9791613}, number={7}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Salah, OMA and Ashby, GS and Bruce, MI and Pederzolli, EA and Walsh, JD}, year={1979}, pages={1613} }

JSON

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  "abstract": "<jats:p>Reactions between silver(1)\nsalts and poly(pyrazolyl)borate anions in the\npresence of donor ligands have given 21 complexes of general formula AgL(RnBH4-n) [L = PPh3, P(c6H4Me)3,\nP(OMe)3, P(OPh)3, AsPh3,\nSbPh3, o - C6H4(\nAsMe2)2 or ButNC; RnBH4-n\n= HB(pz)3, HB(Me2pz)3 orB(pz)4], and [Ag(HBR3)]2(dppe)\n(R = PZ or Me2pz) and {[Ag(HBR3)](dppm)}n (R =\nPZ, n = 1 ; R = Me2pz, n = 2). Their possible structures are\ndiscussed in the light of various spectroscopicdata obtained for them.</jats:p>",
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