DOI: 10.1071/ch9682881. Iron(II) complexes of 2,4-Bis(2-pyridyl)thiazole

Iron(II) complexes of 2,4-Bis(2-pyridyl)thiazole

10.1071/ch9682881

Crossref journal-article

CSIRO Publishing

Australian Journal of Chemistry (67)

Abstract

Mono and bis iron(11) complexes of 2,4-bis(2-pyridyl)thiazole have been described. Conductivity and visible and infrared spectral data suggest that the mono complexes are five-coordinate. The magnetism of the bis complexes, in contrast to that of the mono complexes, shows unusual temperature dependence. This has been ascribed to the presence, in the bis complexes, of a spin-state equilibrium. Bis[2,4-bis(2-pyridyl)thiazole]cobalt(11) perchlorate has been shown to be a simple paramagnetic compound.

Authors 2

HA Goodwin (first)
RN Sylva (additional)

References 0 Referenced 21

None

Dates

Type	When
Created	15 years ago (Sept. 1, 2010, 7:46 p.m.)
Deposited	6 years, 9 months ago (Nov. 20, 2018, 8 p.m.)
Indexed	1 year, 10 months ago (Oct. 16, 2023, 5:45 p.m.)
Issued	57 years, 8 months ago (Jan. 1, 1968)
Published	57 years, 8 months ago (Jan. 1, 1968)
Published Print	57 years, 8 months ago (Jan. 1, 1968)

Funders 0

None

BibTeX

@article{Goodwin_1968, title={Iron(II) complexes of 2,4-Bis(2-pyridyl)thiazole}, volume={21}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9682881}, DOI={10.1071/ch9682881}, number={12}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Goodwin, HA and Sylva, RN}, year={1968}, pages={2881} }

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  "abstract": "<jats:p>Mono and bis iron(11)\ncomplexes of 2,4-bis(2-pyridyl)thiazole have been described. Conductivity and\nvisible and infrared spectral data suggest that the mono complexes are\nfive-coordinate. The magnetism of the bis complexes, in contrast to that of the\nmono complexes, shows unusual temperature dependence. This has been ascribed to\nthe presence, in the bis complexes, of a spin-state equilibrium. Bis[2,4-bis(2-pyridyl)thiazole]cobalt(11) perchlorate has been shown to\nbe a simple paramagnetic compound. \n\n\n\n\n\n\n\n</jats:p>",
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