10.1071/ch9681683
Crossref journal-article
CSIRO Publishing
Australian Journal of Chemistry (67)
Abstract

The potential energy function for interaction of two argon atoms is determined as closely as possible by fitting a multiparameter potential function to experimental data on molecular beam scattering and second virial coefficients, and to the known long-range interaction coefficients. These data are consistent with a range of potential functions between which gas transport properties do not enable a clear choice to be made. In particular, gas viscosities calculated with any of the potential functions show deviations from experiment which are tentatively ascribed to unexpectedly large slip in the viscosity measurements. Third virial coefficients calculated with allowance for the triple-dipole dispersion three-body interaction are close to experimental values whichever function is used, suggesting that other non-additive interactions must be small. Assuming this, the properties of crystalline argon at 0�K are used to specify a single potential function.

Bibliography

Barker, J., & Pompe, A. (1968). Atomic interactions in argon. Australian Journal of Chemistry, 21(7), 1683.

Authors 2
  1. JA Barker (first)
  2. A Pompe (additional)
References 0 Referenced 204

None

Dates
Type When
Created 6 years, 9 months ago (Nov. 21, 2018, 1:04 a.m.)
Deposited 4 years, 5 months ago (March 26, 2021, 1:10 a.m.)
Indexed 3 weeks, 4 days ago (Aug. 7, 2025, 5:07 a.m.)
Issued 57 years, 8 months ago (Jan. 1, 1968)
Published 57 years, 8 months ago (Jan. 1, 1968)
Published Print 57 years, 8 months ago (Jan. 1, 1968)
Funders 0

None

@article{Barker_1968, title={Atomic interactions in argon}, volume={21}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9681683}, DOI={10.1071/ch9681683}, number={7}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Barker, JA and Pompe, A}, year={1968}, pages={1683} }