DOI: 10.1071/ch9641366. Metal chelates derived from 2,4-Bis-(2-pyridyl)thiazole and 2-(2-pyridylamino)-4-(2-pyridyl)thiazole

Metal chelates derived from 2,4-Bis-(2-pyridyl)thiazole and 2-(2-pyridylamino)-4-(2-pyridyl)thiazole

10.1071/ch9641366

Crossref journal-article

CSIRO Publishing

Australian Journal of Chemistry (67)

Abstract

The bases 2,4-bis-(2-pyridyl)thiazole and 2-(2-pyridylamino)-4-(2-pyridyl)thiazole have been prepared by an adaptation of the Hantzsch thiazole synthesis. Each of these bases is capable of functioning as a tridentate chelating agent and yields well-defined chelates with iron(II), coba1t(II), nickel(II), and copper(II) salts. Complexes of the former base are the less stable and this has been ascribed to greater distortion of its bond angles induced on coordination. Neither base yields complexes of comparable stability to corresponding complexes of terpyridine. The complexes of Fe(II), Co(II), and Ni(II) isolated are spin-free.

Bibliography

Goodwin, H. (1964). Metal chelates derived from 2,4-Bis-(2-pyridyl)thiazole and 2-(2-pyridylamino)-4-(2-pyridyl)thiazole. Australian Journal of Chemistry, 17(12), 1366.

Authors 1

HA Goodwin (first)

References 0 Referenced 22

None

Dates

Type	When
Created	15 years ago (Sept. 1, 2010, 7:33 p.m.)
Deposited	6 years, 9 months ago (Nov. 20, 2018, 7:37 p.m.)
Indexed	1 year, 8 months ago (Dec. 13, 2023, 1:20 p.m.)
Issued	61 years, 8 months ago (Jan. 1, 1964)
Published	61 years, 8 months ago (Jan. 1, 1964)
Published Print	61 years, 8 months ago (Jan. 1, 1964)

Funders 0

None

BibTeX

@article{Goodwin_1964, title={Metal chelates derived from 2,4-Bis-(2-pyridyl)thiazole and 2-(2-pyridylamino)-4-(2-pyridyl)thiazole}, volume={17}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch9641366}, DOI={10.1071/ch9641366}, number={12}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Goodwin, HA}, year={1964}, pages={1366} }

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