Abstract
New methods to synthesize and functionalize polymers are of constant interest to the polymer scientist. The 1,3-dipolar cycloaddition between an azide and terminal alkyne has received much attention since the reports that copper(i) provides high yields and regioselective synthesis of 1,4-substituted 1,2,3-triazoles. This coupling chemistry has been rapidly adopted by polymer scientists in the synthesis and post-polymerization modification of polymers. This Review will provide the historical context of the recent development of the copper-mediated azide–alkyne cycloaddition and its use in polymer science, particularly in dendrimer synthesis/functionalization, surface immobilization/modification, orthogonally functionalizing polymers, and its integration with ATRP (atom transfer radical polymerization).
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Dates
Type | When |
---|---|
Created | 18 years, 2 months ago (June 18, 2007, 2:08 a.m.) |
Deposited | 4 years, 5 months ago (March 26, 2021, 12:54 a.m.) |
Indexed | 4 months ago (April 30, 2025, 8:06 p.m.) |
Issued | 18 years, 8 months ago (Jan. 1, 2007) |
Published | 18 years, 8 months ago (Jan. 1, 2007) |
Published Print | 18 years, 8 months ago (Jan. 1, 2007) |
@article{Evans_2007, title={The Rise of Azide–Alkyne 1,3-Dipolar “Click” Cycloaddition and its Application to Polymer Science and Surface Modification}, volume={60}, ISSN={0004-9425}, url={http://dx.doi.org/10.1071/ch06457}, DOI={10.1071/ch06457}, number={6}, journal={Australian Journal of Chemistry}, publisher={CSIRO Publishing}, author={Evans, Richard A.}, year={2007}, pages={384} }