Abstract
A new technique for producing thin films of the high-temperature perovskite superconductors, LnBa2Cu3O7−x, where Ln represents a rare-earth element, using spin-on metalorganic precursors is described. Pyrolysis of the spin-coated films, consisting of mixed metal (2-ethyl hexanoates), leads to black films up to several microns thick whose degree of orientation is a function of the processing temperature and duration. Representative films of YBa2Cu3O7−x on MgO begin to exhibit orientation with the c axis perpendicular to the film plane at heat treatments above 900 °C. The superconducting behavior of a highly oriented film produced at 990 °C is characterized by Tc(onset)=89 K, Tc(R=0)=77 K, and Jc=103 A cm−2 at 65 K.
References
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 8:48 a.m.) |
Deposited | 1 year, 7 months ago (Feb. 2, 2024, 5:15 p.m.) |
Indexed | 2 weeks ago (Aug. 23, 2025, 12:58 a.m.) |
Issued | 37 years, 7 months ago (Jan. 11, 1988) |
Published | 37 years, 7 months ago (Jan. 11, 1988) |
Published Print | 37 years, 7 months ago (Jan. 11, 1988) |
@article{Gross_1988, title={Versatile new metalorganic process for preparing superconducting thin films}, volume={52}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.99038}, DOI={10.1063/1.99038}, number={2}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Gross, M. E. and Hong, M. and Liou, S. H. and Gallagher, P. K. and Kwo, J.}, year={1988}, month=jan, pages={160–162} }