DOI: 10.1063/1.95028. A 14% efficient nonaqueous semiconductor/liquid junction solar cell

A 14% efficient nonaqueous semiconductor/liquid junction solar cell

10.1063/1.95028

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

We describe the most efficient semiconductor/liquid junction solar cell reported to date. Under W-halogen (ELH) illumination, the device is a 14% efficient two-electrode solar cell fabricated from an n-type silicon photoanode in contact with a nonaqueous electrolyte solution. The cell′s central feature is an ultrathin electrolyte layer which simultaneously reduces losses which result from electrode polarization, electrolyte light absorption, and electrolyte resistance. The thin electrolyte layer also eliminates the need for forced convection of the redox couple and allows for precise control over the amount of water (and other electrolyte impurities) exposed to the semiconductor. After one month of continuous operation under ELH light at 100 mW/cm2, which corresponds to the passage of over 70 000 C/cm2, thin-layer cells retained over 90% of their efficiency. In addition, when made with Wacker Silso cast polycrystalline Si, cells yield an efficiency of 9.8% under simulated AMl illumination. The thin-layer cells employ no external compensation yet surpass their corresponding experimental (three-electrode) predecessors in efficiency.

Bibliography

Gibbons, J. F., Cogan, G. W., Gronet, C. M., & Lewis, N. S. (1984). A 14% efficient nonaqueous semiconductor/liquid junction solar cell. Applied Physics Letters, 45(10), 1095â1097.

Authors 4

James F. Gibbons (first)
George W. Cogan (additional)
Chris M. Gronet (additional)
Nathan S. Lewis (additional)

References 19 Referenced 80

{'key': '2024020514323167100_r1', 'first-page': '512', 'volume': '33', 'year': '1978', 'journal-title': 'Appl. Phys. Lett.'} / Appl. Phys. Lett. (1978)
{'key': '2024020514323167100_r1a', 'first-page': '154', 'volume': '12', 'year': '1981', 'journal-title': 'Acc. Chem. Res.'} / Acc. Chem. Res. (1981)
10.1021/bk-1981-0146.ch024 / ACS Symposium Ser. (1981)
10.1126/science.221.4618.1358 / Science (1983)
{'key': '2024020514323167100_r2a', 'first-page': '501', 'volume': '307', 'year': '1984', 'journal-title': 'Nature'} / Nature (1984)
10.1149/1.2133140 / J. Electrochem. Soc. (1977)
10.1073/pnas.74.10.4116 / Proc. Natl. Acad. Sci. (1977)
10.1021/ja00859a007 / J. Amer. Chem. Soc. (1975)
10.1021/ja00531a001 / J. Am. Chem. Soc. (1980)
{'key': '2024020514323167100_r7', 'first-page': '733', 'volume': '300', 'year': '1983', 'journal-title': 'Nature'} / Nature (1983)
10.1038/307533a0 / Nature (1984)
10.1063/1.94148 / Appl. Phys. Lett. (1983)
10.1073/pnas.80.4.1152 / Proc. Natl. Acad. Sci. (1983)
10.1146/annurev.ms.14.080184.000523 / Ann. Rev. Mat. Sci. (1984)
10.1149/1.2129094 / J. Electrochem. Soc. (1979)
10.1149/1.2127248 / J. Electrochem. Soc. (1981)
10.1016/0379-6787(82)90065-5 / Solar Cells (1982)
{'key': '2024020514323167100_r15'}
10.1063/1.94831 / Appl. Phys. Lett. (1984)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 13, 2003, 4:54 p.m.)
Deposited	1 year, 6 months ago (Feb. 5, 2024, 9:33 a.m.)
Indexed	2 days, 14 hours ago (Aug. 27, 2025, 11:40 a.m.)
Issued	40 years, 9 months ago (Nov. 15, 1984)
Published	40 years, 9 months ago (Nov. 15, 1984)
Published Print	40 years, 9 months ago (Nov. 15, 1984)

Funders 0

None

BibTeX

@article{Gibbons_1984, title={A 14% efficient nonaqueous semiconductor/liquid junction solar cell}, volume={45}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.95028}, DOI={10.1063/1.95028}, number={10}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Gibbons, James F. and Cogan, George W. and Gronet, Chris M. and Lewis, Nathan S.}, year={1984}, month=nov, pages={1095–1097} }

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