Abstract
Oxidation of the surface of p-InP with alkaline peroxide and treatment with dilute potassium cyanide increase the efficiency of the p-InP/V2+−V3+ -HCl/C cell to 11.5%. The open circuit voltage of the cell follows the redox potential of the solution over a 0.5 V range. The lack of voltage pinning is consistent with photoemission studies of Spicer et al., showing that adsorption of oxygen on p-InP raises the surface fermi level from a position near the valence band maximum to noe near the conduction band minimum.
References
18
Referenced
103
10.1021/ja00541a029
/ J. Am. Chem. Soc. (1980)10.1021/ja00531a001
/ J. Am. Chem. Soc. (1980)10.1021/ja00531a002
/ J. Am. Chem. Soc. (1980)10.1021/ja00531a003
/ J. Am. Chem. Soc. (1980)10.1063/1.91280
/ Appl. Phys. Lett. (1980)10.1063/1.90422
/ Appl. Phys. Lett. (1978){'key': '2024020512120706600_r7'}
10.1149/1.2129201
/ J. Electrochem. Soc. (1979)10.1002/bbpc.19800840614
/ Ber. Bunsenges. Phys. Chem. (1980)10.1149/1.2129647
/ J. Electrochem. Soc. (1980)10.1021/ja00519a037
/ J. Am. Chem. Soc. (1979)10.1021/ja00526a019
/ J. Am. Chem. Soc. (1980)10.1002/bbpc.19790831010
/ Ber. Bunsenges. Phys. Chem. (1979)10.1063/1.89352
/ Appl. Phys. Lett. (1977){'key': '2024020512120706600_r15', 'first-page': '313', 'volume': '33', 'year': '1978', 'journal-title': 'Appl. Phys. Lett.'}
/ Appl. Phys. Lett. (1978)10.1116/1.570215
/ J. Vac. Sci. Technol. (1979)10.1103/PhysRevLett.44.420
/ Phys. Rev. Lett. (1980){'key': '2024020512120706600_r18', 'first-page': '143', 'volume': '22', 'year': '1969', 'journal-title': 'Phys. Rev. Lett.'}
/ Phys. Rev. Lett. (1969)
Dates
Type | When |
---|---|
Created | 22 years, 6 months ago (Feb. 13, 2003, 4:05 p.m.) |
Deposited | 1 year, 6 months ago (Feb. 5, 2024, 7:43 a.m.) |
Indexed | 4 months, 3 weeks ago (April 3, 2025, 11:23 a.m.) |
Issued | 44 years, 6 months ago (Feb. 15, 1981) |
Published | 44 years, 6 months ago (Feb. 15, 1981) |
Published Print | 44 years, 6 months ago (Feb. 15, 1981) |
@article{Heller_1981, title={11.5% solar conversion efficiency in the photocathodically protected p-InP/V3+-V2+-HCI/C semiconductor liquid junction cell}, volume={38}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.92307}, DOI={10.1063/1.92307}, number={4}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Heller, Adam and Miller, Barry and Thiel, F. A.}, year={1981}, month=feb, pages={282–284} }