DOI: 10.1063/1.5091787. Long-range magnetic ordering in rocksalt-type high-entropy oxides

Long-range magnetic ordering in rocksalt-type high-entropy oxides

10.1063/1.5091787

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

We report the magnetic properties of Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O, a high-entropy oxide with a rocksalt structure, and the influence of substitutions on these properties. From the magnetic susceptibility and neutron diffraction measurements, we found that this compound exhibits long-range magnetic order below 120 K despite the substantial structural disorder. Other rocksalt-type high-entropy oxides with various chemical substitutions were found to host either an antiferromagnetic order or spin-glass state depending on the amount of magnetic ions. The presence of magnetic order for such a disordered material potentially provides a route to explore exotic magnetic properties and functions.

Bibliography

Jimenez-Segura, M. P., Takayama, T., BÃ©rardan, D., Hoser, A., Reehuis, M., Takagi, H., & Dragoe, N. (2019). Long-range magnetic ordering in rocksalt-type high-entropy oxides. Applied Physics Letters, 114(12).

Authors 7

Marco Polo Jimenez-Segura (first)
Tomohiro Takayama (additional)
David Bérardan (additional)
Andreas Hoser (additional)
Manfred Reehuis (additional)
Hidenori Takagi (additional)
Nita Dragoe (additional)

References 25 Referenced 92

10.1002/adem.200300567 / Adv. Eng. Mater. (2004)
10.1038/ncomms9485 / Nat. Commun. (2015)
10.1016/j.scriptamat.2017.08.040 / Scr. Mater. (2018)
10.1016/j.jeurceramsoc.2018.04.063 / J. Eur. Ceram. Soc. (2018)
10.1038/srep37946 / Sci. Rep. (2016)
10.1016/j.ceramint.2018.08.100 / Ceram. Int. (2018)
10.1557/mrc.2018.184 / MRS Commun. (2018)
10.1007/s10853-018-2168-9 / J. Mater. Sci. (2018)
10.1016/j.jeurceramsoc.2016.09.018 / J. Eur. Ceram. Soc. (2017)
10.1002/pssr.201600043 / Phys. Status Solidi RRL (2016)
10.1039/C6TA03249D / J. Mater. Chem. A (2016)
10.1038/s41467-018-05774-5 / Nat. Commun. (2018)
10.1016/j.jallcom.2018.11.049 / J. Alloys Compd. (2019)
10.1038/s41598-017-13810-5 / Sci. Rep. (2017)
10.1016/0921-4526(93)90108-I / Physica B (1993)
{'volume-title': 'International Tables for Crystallography', 'year': '1995', 'author': 'Wilson', 'key': '2023070200252261300_c16'} / International Tables for Crystallography by Wilson (1995)
10.1016/j.jallcom.2017.02.070 / J. Alloys Compd. (2017)
10.1063/1.4962135 / J. Appl. Phys. (2016)
10.1143/PTP.17.177 / Prog. Theor. Phys. (1957)
10.1088/0953-8984/8/1/010 / J. Phys.: Condens. Matter (1996)
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10.1103/PhysRev.110.1333 / Phys. Rev. (1958)
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10.1103/PhysRevB.70.184411 / Phys. Rev. B (2004)
{'key': '2023070200252261300_c25'}

Dates

Type	When
Created	6 years, 5 months ago (March 25, 2019, 12:08 p.m.)
Deposited	2 years, 1 month ago (July 1, 2023, 8:25 p.m.)
Indexed	2 days, 3 hours ago (Aug. 29, 2025, 5:57 a.m.)
Issued	6 years, 5 months ago (March 25, 2019)
Published	6 years, 5 months ago (March 25, 2019)
Published Online	6 years, 5 months ago (March 25, 2019)
Published Print	6 years, 5 months ago (March 25, 2019)

Funders 3

Centre National de la Recherche Scientifique 10.13039/501100004794
Region: Europe
gov (Research institutes and centers)
Labels4
1. National Centre for Scientific Research
2. French National Centre for Scientific Research
3. Le Centre national de la recherche scientifique
4. CNRS
Awards1
1. Energy program,2017
Alexander von Humboldt-Stiftung 10.13039/100005156
Region: Europe
pri (Trusts, charities, foundations (both public and private))
Labels5
1. Humboldt-Stiftung
2. Humboldt Foundation
3. Alexander von Humboldt Foundation
4. Humboldt Stiftung
5. AvH
Japan Society for the Promotion of Science 10.13039/501100001691
Region: Asia
gov (National government)
Labels6
1. KAKENHI
2. 日本学術振興会
3. Gakushin
4. JSPS KAKEN
5. JSPS Grants-in-Aid for Scientific Research
6. JSPS
Awards2
1. KAKENHI JP15H05852,JP15K21717,17H01140
2. Core-to-core program

BibTeX

@article{Jimenez_Segura_2019, title={Long-range magnetic ordering in rocksalt-type high-entropy oxides}, volume={114}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.5091787}, DOI={10.1063/1.5091787}, number={12}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Jimenez-Segura, Marco Polo and Takayama, Tomohiro and Bérardan, David and Hoser, Andreas and Reehuis, Manfred and Takagi, Hidenori and Dragoe, Nita}, year={2019}, month=mar }

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