DOI: 10.1063/1.4907972. Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence

Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence

10.1063/1.4907972

Crossref journal-article

AIP Publishing

Applied Physics Letters (317)

Abstract

Second harmonic generation (SHG) of a high intensity was found in MoS2 flakes of different thicknesses exfoliated on a silicon substrate. Reduction of the SHG intensity was observed only for a small portion of flakes, for both very thin and quite thick ones. This was attributed to the presence of polytypism, i.e., of 3R non-centrosymmetric and 2H centrosymmetric polytypes, in a source bulk crystal grown by the chemical vapor transport technique. The presence of two polytypes in the sample was confirmed by the spectral structure of the photoluminescence of bound excitons observed in flakes at low temperature. Absolute values of nonlinear susceptibility of MoS2 flakes of different thicknesses were estimated.

Bibliography

Mishina, E., Sherstyuk, N., Lavrov, S., Sigov, A., Mitioglu, A., Anghel, S., & Kulyuk, L. (2015). Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence. Applied Physics Letters, 106(13).

Authors 7

E. Mishina (first)
N. Sherstyuk (additional)
S. Lavrov (additional)
A. Sigov (additional)
A. Mitioglu (additional)
S. Anghel (additional)
L. Kulyuk (additional)

References 28 Referenced 42

10.1038/nnano.2012.193 / Nat. Nanotechnol. (2012)
10.1038/nnano.2010.279 / Nat. Nanotechnol. (2011)
10.1126/science.1235547 / Science (2013)
10.1021/nn305301b / ACS Nano (2013)
10.1038/nnano.2013.100 / Nat. Nanotechnol. (2013)
10.1103/PhysRevB.69.134111 / Phys. Rev. (2004)
10.1103/PhysRevB.90.115438 / Phys. Rev. B (2014)
10.1038/nnano.2014.148 / Nat. Nanotechnol. (2014)
10.1038/nphys2524 / Nat. Phys. (2013)
10.1038/srep05209 / Sci. Rep. (2014)
10.1021/nl401561r / Nano Lett. (2013)
10.1103/PhysRevB.89.235410 / Phys. Rev. B (2014)
10.1103/PhysRevB.87.161403 / Phys. Rev. B (2013)
10.1016/0022-4596(85)90198-7 / J. Solid State Chem. (1985)
10.1021/cg400953e / Cryst. Growth Des. (2013)
10.1038/nature04233 / Nature (2005)
10.1007/BF02606398 / J. Appl. Spectrosc. (1994)
{'volume-title': 'The Principles of Nonlinear Optics', 'year': '1984', 'key': '2023061800030037000_c18'} / The Principles of Nonlinear Optics (1984)
10.1063/1.108716 / Appl. Phys. Lett. (1993)
10.1021/nn500228r / ACS Nano (2014)
10.1103/PhysRevB.87.201401 / Phys. Rev. B (2013)
10.1088/0957-4484/22/12/125706 / Nanotechnology (2011)
10.1038/srep05530 / Sci. Rep. (2014)
10.1103/PhysRevB.68.075314 / Phys. Rev. B (2003)
10.1103/PhysRevB.72.075336 / Phys. Rev. B (2005)
10.1007/978-3-642-81368-9 / Excitons by Cho (1979)
10.1103/PhysRevB.21.2401 / Phys. Rev. B by Weber (1980)
S. Anghel, Yu. Chumakov, V. Kravtsov, A. Mitioglu, P. Płochocka, K. Sushkevich, G. Volodina, A. Colev, and L. Kulyuk, e-print arXiv:1411.3850[cond-mat.mtrl-sci].

Dates

Type	When
Created	10 years, 5 months ago (April 1, 2015, 8:46 a.m.)
Deposited	2 years, 2 months ago (June 17, 2023, 8:03 p.m.)
Indexed	1 month ago (July 30, 2025, 7:04 a.m.)
Issued	10 years, 5 months ago (March 30, 2015)
Published	10 years, 5 months ago (March 30, 2015)
Published Online	10 years, 5 months ago (March 31, 2015)
Published Print	10 years, 5 months ago (March 30, 2015)

Funders 0

None

BibTeX

@article{Mishina_2015, title={Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence}, volume={106}, ISSN={1077-3118}, url={http://dx.doi.org/10.1063/1.4907972}, DOI={10.1063/1.4907972}, number={13}, journal={Applied Physics Letters}, publisher={AIP Publishing}, author={Mishina, E. and Sherstyuk, N. and Lavrov, S. and Sigov, A. and Mitioglu, A. and Anghel, S. and Kulyuk, L.}, year={2015}, month=mar }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        30
      ]
    ],
    "date-time": "2025-07-30T11:04:22Z",
    "timestamp": 1753873462257,
    "version": "3.41.2"
  },
  "reference-count": 28,
  "publisher": "AIP Publishing",
  "issue": "13",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2015,
        3,
        30
      ]
    ]
  },
  "abstract": "<jats:p>Second harmonic generation (SHG) of a high intensity was found in MoS2 flakes of different thicknesses exfoliated on a silicon substrate. Reduction of the SHG intensity was observed only for a small portion of flakes, for both very thin and quite thick ones. This was attributed to the presence of polytypism, i.e., of 3R non-centrosymmetric and 2H centrosymmetric polytypes, in a source bulk crystal grown by the chemical vapor transport technique. The presence of two polytypes in the sample was confirmed by the spectral structure of the photoluminescence of bound excitons observed in flakes at low temperature. Absolute values of nonlinear susceptibility of MoS2 flakes of different thicknesses were estimated.</jats:p>",
  "DOI": "10.1063/1.4907972",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2015,
        4,
        1
      ]
    ],
    "date-time": "2015-04-01T12:46:06Z",
    "timestamp": 1427892366000
  },
  "update-policy": "https://doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 42,
  "title": "Observation of two polytypes of MoS2 ultrathin layers studied by second harmonic generation microscopy and photoluminescence",
  "prefix": "10.1063",
  "volume": "106",
  "author": [
    {
      "given": "E.",
      "family": "Mishina",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Moscow State Technical University of Radio Engineering 1 , Electronics and Automation, 119454 Moscow, Russia"
        }
      ]
    },
    {
      "given": "N.",
      "family": "Sherstyuk",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Moscow State Technical University of Radio Engineering 1 , Electronics and Automation, 119454 Moscow, Russia"
        }
      ]
    },
    {
      "ORCID": "https://orcid.org/0000-0003-0772-1380",
      "authenticated-orcid": false,
      "given": "S.",
      "family": "Lavrov",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Moscow State Technical University of Radio Engineering 1 , Electronics and Automation, 119454 Moscow, Russia"
        }
      ]
    },
    {
      "given": "A.",
      "family": "Sigov",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Moscow State Technical University of Radio Engineering 1 , Electronics and Automation, 119454 Moscow, Russia"
        }
      ]
    },
    {
      "given": "A.",
      "family": "Mitioglu",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Institute of Applied Physics 2 , Academy of Sciences of Moldova, Chisinau MD-2028, Republic of Moldova"
        },
        {
          "name": "Laboratoire National des Champs Magn\u00e9tiques Intenses 3 , Avenue de Rangueil 143, Toulouse 31400, France"
        }
      ]
    },
    {
      "given": "S.",
      "family": "Anghel",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Institute of Applied Physics 2 , Academy of Sciences of Moldova, Chisinau MD-2028, Republic of Moldova"
        },
        {
          "name": "Ruhr-Universit\u00e4t Bochum 4 Anorganische Chemie III, , Universit\u00e4tsstrasse 150, D-44801 Bochum, Germany"
        }
      ]
    },
    {
      "given": "L.",
      "family": "Kulyuk",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Institute of Applied Physics 2 , Academy of Sciences of Moldova, Chisinau MD-2028, Republic of Moldova"
        }
      ]
    }
  ],
  "member": "317",
  "published-online": {
    "date-parts": [
      [
        2015,
        3,
        31
      ]
    ]
  },
  "reference": [
    {
      "key": "2023061800030037000_c1",
      "doi-asserted-by": "publisher",
      "first-page": "699",
      "DOI": "10.1038/nnano.2012.193",
      "volume": "7",
      "year": "2012",
      "journal-title": "Nat. Nanotechnol."
    },
    {
      "key": "2023061800030037000_c2",
      "doi-asserted-by": "publisher",
      "first-page": "147",
      "DOI": "10.1038/nnano.2010.279",
      "volume": "6",
      "year": "2011",
      "journal-title": "Nat. Nanotechnol."
    },
    {
      "key": "2023061800030037000_c3",
      "doi-asserted-by": "publisher",
      "first-page": "1311",
      "DOI": "10.1126/science.1235547",
      "volume": "340",
      "year": "2013",
      "journal-title": "Science"
    },
    {
      "key": "2023061800030037000_c4",
      "doi-asserted-by": "publisher",
      "first-page": "3905",
      "DOI": "10.1021/nn305301b",
      "volume": "7",
      "year": "2013",
      "journal-title": "ACS Nano"
    },
    {
      "key": "2023061800030037000_c5",
      "doi-asserted-by": "publisher",
      "first-page": "497",
      "DOI": "10.1038/nnano.2013.100",
      "volume": "8",
      "year": "2013",
      "journal-title": "Nat. Nanotechnol."
    },
    {
      "key": "2023061800030037000_c6",
      "doi-asserted-by": "publisher",
      "first-page": "134111",
      "DOI": "10.1103/PhysRevB.69.134111",
      "volume": "69",
      "year": "2004",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "2023061800030037000_c7",
      "doi-asserted-by": "publisher",
      "first-page": "115438",
      "DOI": "10.1103/PhysRevB.90.115438",
      "volume": "90",
      "year": "2014",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c8",
      "doi-asserted-by": "publisher",
      "first-page": "611",
      "DOI": "10.1038/nnano.2014.148",
      "volume": "9",
      "year": "2014",
      "journal-title": "Nat. Nanotechnol."
    },
    {
      "key": "2023061800030037000_c9",
      "doi-asserted-by": "publisher",
      "first-page": "149",
      "DOI": "10.1038/nphys2524",
      "volume": "9",
      "year": "2013",
      "journal-title": "Nat. Phys."
    },
    {
      "key": "2023061800030037000_c10",
      "doi-asserted-by": "publisher",
      "first-page": "5209",
      "DOI": "10.1038/srep05209",
      "volume": "4",
      "year": "2014",
      "journal-title": "Sci. Rep."
    },
    {
      "key": "2023061800030037000_c11",
      "doi-asserted-by": "publisher",
      "first-page": "3329",
      "DOI": "10.1021/nl401561r",
      "volume": "13",
      "year": "2013",
      "journal-title": "Nano Lett."
    },
    {
      "key": "2023061800030037000_c12",
      "doi-asserted-by": "publisher",
      "first-page": "235410",
      "DOI": "10.1103/PhysRevB.89.235410",
      "volume": "89",
      "year": "2014",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c13",
      "doi-asserted-by": "publisher",
      "first-page": "161403",
      "DOI": "10.1103/PhysRevB.87.161403",
      "volume": "87",
      "year": "2013",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c14",
      "doi-asserted-by": "publisher",
      "first-page": "351",
      "DOI": "10.1016/0022-4596(85)90198-7",
      "volume": "57",
      "year": "1985",
      "journal-title": "J. Solid State Chem."
    },
    {
      "key": "2023061800030037000_c15",
      "doi-asserted-by": "publisher",
      "first-page": "4453",
      "DOI": "10.1021/cg400953e",
      "volume": "13",
      "year": "2013",
      "journal-title": "Cryst. Growth Des."
    },
    {
      "key": "2023061800030037000_c16",
      "doi-asserted-by": "publisher",
      "first-page": "197",
      "DOI": "10.1038/nature04233",
      "volume": "438",
      "year": "2005",
      "journal-title": "Nature"
    },
    {
      "key": "2023061800030037000_c17",
      "doi-asserted-by": "publisher",
      "first-page": "532",
      "DOI": "10.1007/BF02606398",
      "volume": "61",
      "year": "1994",
      "journal-title": "J. Appl. Spectrosc."
    },
    {
      "volume-title": "The Principles of Nonlinear Optics",
      "year": "1984",
      "key": "2023061800030037000_c18"
    },
    {
      "key": "2023061800030037000_c19",
      "doi-asserted-by": "publisher",
      "first-page": "1314",
      "DOI": "10.1063/1.108716",
      "volume": "62",
      "year": "1993",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023061800030037000_c20",
      "doi-asserted-by": "publisher",
      "first-page": "2951",
      "DOI": "10.1021/nn500228r",
      "volume": "8",
      "year": "2014",
      "journal-title": "ACS Nano"
    },
    {
      "key": "2023061800030037000_c21",
      "doi-asserted-by": "publisher",
      "first-page": "201401",
      "DOI": "10.1103/PhysRevB.87.201401",
      "volume": "87",
      "year": "2013",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c22",
      "doi-asserted-by": "publisher",
      "first-page": "125706",
      "DOI": "10.1088/0957-4484/22/12/125706",
      "volume": "22",
      "year": "2011",
      "journal-title": "Nanotechnology"
    },
    {
      "key": "2023061800030037000_c23",
      "doi-asserted-by": "publisher",
      "first-page": "5530",
      "DOI": "10.1038/srep05530",
      "volume": "4",
      "year": "2014",
      "journal-title": "Sci. Rep."
    },
    {
      "key": "2023061800030037000_c24",
      "doi-asserted-by": "publisher",
      "first-page": "075314",
      "DOI": "10.1103/PhysRevB.68.075314",
      "volume": "68",
      "year": "2003",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c25",
      "doi-asserted-by": "publisher",
      "first-page": "075336",
      "DOI": "10.1103/PhysRevB.72.075336",
      "volume": "72",
      "year": "2005",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c26a",
      "doi-asserted-by": "crossref",
      "first-page": "55",
      "DOI": "10.1007/978-3-642-81368-9",
      "volume-title": "Excitons",
      "author": "Cho",
      "year": "1979"
    },
    {
      "key": "2023061800030037000_c26b",
      "doi-asserted-by": "publisher",
      "first-page": "2401",
      "DOI": "10.1103/PhysRevB.21.2401",
      "volume": "21",
      "author": "Weber",
      "year": "1980",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023061800030037000_c27",
      "unstructured": "S.\u2008Anghel, Yu.\u2008Chumakov, V.\u2008Kravtsov, A.\u2008Mitioglu, P.\u2008P\u0142ochocka, K.\u2008Sushkevich, G.\u2008Volodina, A.\u2008Colev, and L.\u2008Kulyuk, e-print arXiv:1411.3850[cond-mat.mtrl-sci]."
    }
  ],
  "container-title": "Applied Physics Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.4907972/13917013/131901_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.4907972/13917013/131901_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        6,
        18
      ]
    ],
    "date-time": "2023-06-18T00:03:10Z",
    "timestamp": 1687046590000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/apl/article/106/13/131901/26997/Observation-of-two-polytypes-of-MoS2-ultrathin"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2015,
        3,
        30
      ]
    ]
  },
  "references-count": 28,
  "journal-issue": {
    "issue": "13",
    "published-print": {
      "date-parts": [
        [
          2015,
          3,
          30
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.4907972",
  "relation": {},
  "ISSN": [
    "0003-6951",
    "1077-3118"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2015,
        3,
        30
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2015,
        3,
        30
      ]
    ]
  },
  "article-number": "131901"
}