DOI: 10.1063/1.481575. Physical adsorption of xenon in open single walled carbon nanotubes: Observation of a quasi-one-dimensional confined Xe phase

Physical adsorption of xenon in open single walled carbon nanotubes: Observation of a quasi-one-dimensional confined Xe phase

10.1063/1.481575

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The adsorption of Xe into carbon single walled nanotubes with both closed and open ends has been investigated using temperature programmed desorption and other surface analytical tools. It has been found that opening the ends of the nanotube by chemical cutting increases both the kinetic rate and the saturation capacity of the nanotubes for Xe at 95 K. Further enhancement in Xe adsorption kinetics and capacity are achieved by treating the nanotubes in vacuum at 1073 K where CO, CO2, CH4, and H2 are evolved. On this basis it is postulated that surface functionalities such as −COOH block entry ports for adsorption at the nanotube ends and at the defect sites on the walls. The thermal destruction of these functionalities leads to enhanced adsorption. The denser phase of Xe inside the saturated nanotubes desorbs by zero-order kinetics (Ed=26.8±0.6 kJ/mol). It is postulated that a quasi-one-dimensional Xe confined phase in equilibrium, with a two-dimensional Xe gas phase on the exterior, provides a phase transition governing the zero-order kinetics desorption process.

Authors 4

A. Kuznetsova (first)
J. T. Yates (additional)
J. Liu (additional)
R. E. Smalley (additional)

References 43 Referenced 199

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{'key': '2024020611071506100_r3'}
{'key': '2024020611071506100_r4'}
10.1016/S0926-860X(98)00177-X / Appl. Catal., A (1998)
10.1126/science.280.5367.1253 / Science (1998)
10.1007/s003390050744 / Appl. Phys. A: Mater. Sci. Process. (1998)
10.1038/372159a0 / Nature (London) (1994)
10.1016/S0022-0248(96)00833-0 / J. Cryst. Growth (1997)
{'key': '2024020611071506100_r10', 'first-page': '2752', 'volume': '8', 'year': '1996', 'journal-title': 'J. Mater. Chem.'} / J. Mater. Chem. (1996)
10.1021/la00010a059 / Langmuir (1995)
10.1103/PhysRevLett.69.2689 / Phys. Rev. Lett. (1992)
10.1063/1.475261 / J. Chem. Phys. (1997)
10.1023/A:1022558800315 / J. Low Temp. Phys. (1998)
10.1016/S0039-6028(97)00632-8 / Surf. Sci. (1998)
10.1063/1.478114 / J. Chem. Phys. (1999)
10.1126/science.277.5328.933 / Science (1997)
10.1038/386377a0 / Nature (London) (1997)
10.1063/1.123833 / Appl. Phys. Lett. (1999)
{'key': '2024020611071506100_r20', 'first-page': '46', 'volume': '102', 'year': '1998', 'journal-title': 'Langmuir'} / Langmuir (1998)
10.1016/S0009-2614(99)00311-5 / Chem. Phys. Lett. (1999)
10.1038/34139 / Nature (London) (1998)
10.1038/34145 / Nature (London) (1998)
{'key': '2024020611071506100_r24'}
10.1116/1.578799 / J. Vac. Sci. Technol. A (1993)
{'key': '2024020611071506100_r26'}
10.1116/1.575453 / J. Vac. Sci. Technol. A (1988)
10.1016/0039-6028(74)90133-2 / Surf. Sci. (1974)
10.1103/PhysRevB.57.4111 / Phys. Rev. B (1998)
10.1016/0039-6028(74)90037-5 / Surf. Sci. (1974)
{'key': '2024020611071506100_r31'}
{'key': '2024020611071506100_r32', 'first-page': '765', 'volume': '19', 'year': '1998', 'journal-title': 'Chem. J. Chin. Univ.'} / Chem. J. Chin. Univ. (1998)
10.1103/PhysRevLett.82.2548 / Phys. Rev. Lett. (1999)
{'key': '2024020611071506100_r34'}
{'key': '2024020611071506100_r35'}
10.1051/mmm:0199400504-6028300 / Microsc. Microanal. Microstruct. (1994)
10.1103/PhysRevB.57.4111 / Phys. Rev. B (1998)
10.1016/0039-6028(77)90054-1 / Surf. Sci. (1977)
10.1103/PhysRevB.28.6416 / Phys. Rev. B (1983)
{'key': '2024020611071506100_r40'}
10.1063/1.454434 / J. Chem. Phys. (1988)
10.1103/PhysRevLett.82.5305 / Phys. Rev. Lett. (1999)
10.1063/1.453409 / J. Chem. Phys. (1987)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:32 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 6:33 a.m.)
Indexed	1 month, 3 weeks ago (July 1, 2025, 9:06 a.m.)
Issued	25 years, 2 months ago (June 1, 2000)
Published	25 years, 2 months ago (June 1, 2000)
Published Print	25 years, 2 months ago (June 1, 2000)

Funders 0

None

BibTeX

@article{Kuznetsova_2000, title={Physical adsorption of xenon in open single walled carbon nanotubes: Observation of a quasi-one-dimensional confined Xe phase}, volume={112}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.481575}, DOI={10.1063/1.481575}, number={21}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kuznetsova, A. and Yates, J. T. and Liu, J. and Smalley, R. E.}, year={2000}, month=jun, pages={9590–9598} }

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