DOI: 10.1063/1.481167. Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles

Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles

10.1063/1.481167

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Ultrafast laser experiments were used to study electron-phonon coupling in Au nanoparticles in the 2.5 to 8 nm size range in aqueous solution. The electron-phonon coupling constants for these samples were found to be independent of the particle size. This is attributed to a weak interaction between the electron gas and the surface phonon modes in Au. Calculations were performed which show that the coupling between the hot electrons and the surface accounts for less than 10% of the total electron energy losses for these particles. Thus, bulk electron-phonon coupling dominates the relaxation of excited electrons in Au particles, for particles as small as several hundred atoms.

Bibliography

Hodak, J. H., Henglein, A., & Hartland, G. V. (2000). Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles. The Journal of Chemical Physics, 112(13), 5942â5947.

Authors 3

José H. Hodak (first)
Arnim Henglein (additional)
Gregory V. Hartland (additional)

References 42 Referenced 191

10.1103/PhysRevLett.75.4702 / Phys. Rev. Lett. (1995)
10.1063/1.468545 / J. Chem. Phys. (1995)
10.1016/S0009-2614(97)00339-4 / Chem. Phys. Lett. (1997)
10.1021/jp960484e / J. Phys. Chem. (1996)
10.1021/jp962923f / J. Phys. Chem. B (1997)
10.1103/PhysRevB.53.15497 / Phys. Rev. B (1996)
10.1103/PhysRevLett.78.3575 / Phys. Rev. Lett. (1997)
10.1016/S0009-2614(97)01369-9 / Chem. Phys. Lett. (1998)
10.1021/jp9809787 / J. Phys. Chem. B (1998)
10.1063/1.479310 / J. Chem. Phys. (1999)
10.1007/s003400050645 / Appl. Phys. B: Lasers Opt. (1999)
10.1063/1.480202 / J. Chem. Phys. (1999)
10.1364/JOSAB.6.000787 / J. Opt. Soc. Am. B (1989)
10.1063/1.112155 / Appl. Phys. Lett. (1994)
10.1364/JOSAB.11.001236 / J. Opt. Soc. Am. B (1994)
10.1002/(SICI)1521-4095(199803)10:4<338::AID-ADMA338>3.0.CO;2-V / Adv. Mater. (1998)
10.1143/JJAP.37.L1520 / Jpn. J. Appl. Phys. (1998)
10.1364/JOSAB.6.000787 / J. Opt. Soc. Am. B (1989)
10.1016/S0009-2614(98)00277-2 / Chem. Phys. Lett. (1998)
10.1364/JOSAB.12.002372 / J. Opt. Soc. Am. B (1995)
10.1016/0039-6028(85)90239-0 / Surf. Sci. (1985)
{'key': '2024020708244797900_r19'}
10.1021/la981278w / Langmuir (1998)
10.1021/la9901579 / Langmuir (1999)
10.1021/jp962922n / J. Phys. Chem. B (1997)
10.1021/jp9917648 / J. Phys. Chem. B (1999)
10.1103/PhysRevLett.80.4249 / Phys. Rev. Lett. (1998)
10.1103/PhysRevLett.77.3873 / Phys. Rev. Lett. (1996)
10.1103/PhysRevB.48.12365 / Phys. Rev. B (1993)
10.1103/PhysRevB.50.15337 / Phys. Rev. B (1994)
{'key': '2024020708244797900_r27'}
10.1103/PhysRevLett.64.784 / Phys. Rev. Lett. (1990)
10.1103/PhysRevB.51.11433 / Phys. Rev. B (1995)
10.1103/PhysRevB.46.13592 / Phys. Rev. B (1992)
10.1103/PhysRevLett.68.2834 / Phys. Rev. Lett. (1992)
10.1103/PhysRevB.50.8957 / Phys. Rev. B (1994)
10.1103/PhysRevLett.76.535 / Phys. Rev. Lett. (1996)
10.1103/PhysRevB.55.10869 / Phys. Rev. B (1997)
10.1016/0039-6028(90)90626-J / Surf. Sci. (1990)
10.1080/00207219208925745 / Int. J. Electron. (1992)
10.1103/PhysRevLett.73.1231 / Phys. Rev. Lett. (1994)
10.1364/AO.38.003614 / Appl. Opt. (1999)

Dates

Type	When
Created	23 years ago (July 26, 2002, 8:29 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 9:15 a.m.)
Indexed	1 year ago (July 22, 2024, 2:33 p.m.)
Issued	25 years, 4 months ago (April 1, 2000)
Published	25 years, 4 months ago (April 1, 2000)
Published Print	25 years, 4 months ago (April 1, 2000)

Funders 0

None

BibTeX

@article{Hodak_2000, title={Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles}, volume={112}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.481167}, DOI={10.1063/1.481167}, number={13}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hodak, José H. and Henglein, Arnim and Hartland, Gregory V.}, year={2000}, month=apr, pages={5942–5947} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        7,
        22
      ]
    ],
    "date-time": "2024-07-22T18:33:59Z",
    "timestamp": 1721673239870
  },
  "reference-count": 42,
  "publisher": "AIP Publishing",
  "issue": "13",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2000,
        4,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Ultrafast laser experiments were used to study electron-phonon coupling in Au nanoparticles in the 2.5 to 8 nm size range in aqueous solution. The electron-phonon coupling constants for these samples were found to be independent of the particle size. This is attributed to a weak interaction between the electron gas and the surface phonon modes in Au. Calculations were performed which show that the coupling between the hot electrons and the surface accounts for less than 10% of the total electron energy losses for these particles. Thus, bulk electron-phonon coupling dominates the relaxation of excited electrons in Au particles, for particles as small as several hundred atoms.</jats:p>",
  "DOI": "10.1063/1.481167",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T12:29:57Z",
    "timestamp": 1027686597000
  },
  "page": "5942-5947",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 191,
  "title": "Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles",
  "prefix": "10.1063",
  "volume": "112",
  "author": [
    {
      "given": "Jos\u00e9 H.",
      "family": "Hodak",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana\u200946556-5670"
        }
      ]
    },
    {
      "given": "Arnim",
      "family": "Henglein",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Notre Dame Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana\u200946556-5670"
        }
      ]
    },
    {
      "given": "Gregory V.",
      "family": "Hartland",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana\u200946556-5670"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020708244797900_r1",
      "doi-asserted-by": "crossref",
      "first-page": "4702",
      "DOI": "10.1103/PhysRevLett.75.4702",
      "volume": "75",
      "year": "1995",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r2",
      "doi-asserted-by": "crossref",
      "first-page": "3860",
      "DOI": "10.1063/1.468545",
      "volume": "102",
      "year": "1995",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020708244797900_r2a",
      "doi-asserted-by": "crossref",
      "first-page": "139",
      "DOI": "10.1016/S0009-2614(97)00339-4",
      "volume": "270",
      "year": "1997",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020708244797900_r3",
      "doi-asserted-by": "crossref",
      "first-page": "8053",
      "DOI": "10.1021/jp960484e",
      "volume": "100",
      "year": "1996",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024020708244797900_r3a",
      "doi-asserted-by": "crossref",
      "first-page": "3713",
      "DOI": "10.1021/jp962923f",
      "volume": "101",
      "year": "1997",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2024020708244797900_r4",
      "doi-asserted-by": "crossref",
      "first-page": "15497",
      "DOI": "10.1103/PhysRevB.53.15497",
      "volume": "53",
      "year": "1996",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r5",
      "doi-asserted-by": "crossref",
      "first-page": "3575",
      "DOI": "10.1103/PhysRevLett.78.3575",
      "volume": "78",
      "year": "1997",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r6",
      "doi-asserted-by": "crossref",
      "first-page": "135",
      "DOI": "10.1016/S0009-2614(97)01369-9",
      "volume": "284",
      "year": "1998",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020708244797900_r6a",
      "doi-asserted-by": "crossref",
      "first-page": "6958",
      "DOI": "10.1021/jp9809787",
      "volume": "102",
      "year": "1998",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2024020708244797900_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1255",
      "DOI": "10.1063/1.479310",
      "volume": "111",
      "year": "1999",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020708244797900_r8",
      "doi-asserted-by": "crossref",
      "first-page": "433",
      "DOI": "10.1007/s003400050645",
      "volume": "68",
      "year": "1999",
      "journal-title": "Appl. Phys. B: Lasers Opt."
    },
    {
      "key": "2024020708244797900_r9",
      "doi-asserted-by": "crossref",
      "first-page": "8613",
      "DOI": "10.1063/1.480202",
      "volume": "111",
      "year": "1999",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020708244797900_r10",
      "doi-asserted-by": "crossref",
      "first-page": "787",
      "DOI": "10.1364/JOSAB.6.000787",
      "volume": "6",
      "year": "1989",
      "journal-title": "J. Opt. Soc. Am. B"
    },
    {
      "key": "2024020708244797900_r11",
      "doi-asserted-by": "crossref",
      "first-page": "941",
      "DOI": "10.1063/1.112155",
      "volume": "65",
      "year": "1994",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2024020708244797900_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1236",
      "DOI": "10.1364/JOSAB.11.001236",
      "volume": "11",
      "year": "1994",
      "journal-title": "J. Opt. Soc. Am. B"
    },
    {
      "key": "2024020708244797900_r13",
      "doi-asserted-by": "crossref",
      "first-page": "338",
      "DOI": "10.1002/(SICI)1521-4095(199803)10:4<338::AID-ADMA338>3.0.CO;2-V",
      "volume": "10",
      "year": "1998",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "2024020708244797900_r14",
      "doi-asserted-by": "crossref",
      "first-page": "L1520",
      "DOI": "10.1143/JJAP.37.L1520",
      "volume": "37",
      "year": "1998",
      "journal-title": "Jpn. J. Appl. Phys."
    },
    {
      "key": "2024020708244797900_r15",
      "doi-asserted-by": "crossref",
      "first-page": "787",
      "DOI": "10.1364/JOSAB.6.000787",
      "volume": "6",
      "year": "1989",
      "journal-title": "J. Opt. Soc. Am. B"
    },
    {
      "key": "2024020708244797900_r16",
      "doi-asserted-by": "crossref",
      "first-page": "243",
      "DOI": "10.1016/S0009-2614(98)00277-2",
      "volume": "288",
      "year": "1998",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020708244797900_r17",
      "doi-asserted-by": "crossref",
      "first-page": "2372",
      "DOI": "10.1364/JOSAB.12.002372",
      "volume": "12",
      "year": "1995",
      "journal-title": "J. Opt. Soc. Am. B"
    },
    {
      "key": "2024020708244797900_r18",
      "doi-asserted-by": "crossref",
      "first-page": "678",
      "DOI": "10.1016/0039-6028(85)90239-0",
      "volume": "156",
      "year": "1985",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020708244797900_r19"
    },
    {
      "key": "2024020708244797900_r20",
      "doi-asserted-by": "crossref",
      "first-page": "7392",
      "DOI": "10.1021/la981278w",
      "volume": "14",
      "year": "1998",
      "journal-title": "Langmuir"
    },
    {
      "key": "2024020708244797900_r21",
      "doi-asserted-by": "crossref",
      "first-page": "6738",
      "DOI": "10.1021/la9901579",
      "volume": "15",
      "year": "1999",
      "journal-title": "Langmuir"
    },
    {
      "key": "2024020708244797900_r22",
      "doi-asserted-by": "crossref",
      "first-page": "3706",
      "DOI": "10.1021/jp962922n",
      "volume": "101",
      "year": "1997",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2024020708244797900_r23",
      "doi-asserted-by": "crossref",
      "first-page": "8410",
      "DOI": "10.1021/jp9917648",
      "volume": "103",
      "year": "1999",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2024020708244797900_r24",
      "doi-asserted-by": "crossref",
      "first-page": "4249",
      "DOI": "10.1103/PhysRevLett.80.4249",
      "volume": "80",
      "year": "1998",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r25",
      "doi-asserted-by": "crossref",
      "first-page": "3873",
      "DOI": "10.1103/PhysRevLett.77.3873",
      "volume": "77",
      "year": "1996",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r26",
      "doi-asserted-by": "crossref",
      "first-page": "12365",
      "DOI": "10.1103/PhysRevB.48.12365",
      "volume": "48",
      "year": "1993",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r26a",
      "doi-asserted-by": "crossref",
      "first-page": "15337",
      "DOI": "10.1103/PhysRevB.50.15337",
      "volume": "50",
      "year": "1994",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r27"
    },
    {
      "key": "2024020708244797900_r28",
      "doi-asserted-by": "crossref",
      "first-page": "784",
      "DOI": "10.1103/PhysRevLett.64.784",
      "volume": "64",
      "year": "1990",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r28a",
      "doi-asserted-by": "crossref",
      "first-page": "11433",
      "DOI": "10.1103/PhysRevB.51.11433",
      "volume": "51",
      "year": "1995",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r29",
      "doi-asserted-by": "crossref",
      "first-page": "13592",
      "DOI": "10.1103/PhysRevB.46.13592",
      "volume": "46",
      "year": "1992",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r29a",
      "doi-asserted-by": "crossref",
      "first-page": "2834",
      "DOI": "10.1103/PhysRevLett.68.2834",
      "volume": "68",
      "year": "1992",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r30",
      "doi-asserted-by": "crossref",
      "first-page": "R8957",
      "DOI": "10.1103/PhysRevB.50.8957",
      "volume": "50",
      "year": "1994",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r31",
      "doi-asserted-by": "crossref",
      "first-page": "535",
      "DOI": "10.1103/PhysRevLett.76.535",
      "volume": "76",
      "year": "1996",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r32",
      "doi-asserted-by": "crossref",
      "first-page": "10869",
      "DOI": "10.1103/PhysRevB.55.10869",
      "volume": "55",
      "year": "1997",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024020708244797900_r33",
      "doi-asserted-by": "crossref",
      "first-page": "143",
      "DOI": "10.1016/0039-6028(90)90626-J",
      "volume": "239",
      "year": "1990",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "2024020708244797900_r34",
      "doi-asserted-by": "crossref",
      "first-page": "955",
      "DOI": "10.1080/00207219208925745",
      "volume": "73",
      "year": "1992",
      "journal-title": "Int. J. Electron."
    },
    {
      "key": "2024020708244797900_r35",
      "doi-asserted-by": "crossref",
      "first-page": "1231",
      "DOI": "10.1103/PhysRevLett.73.1231",
      "volume": "73",
      "year": "1994",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020708244797900_r36",
      "doi-asserted-by": "crossref",
      "first-page": "3614",
      "DOI": "10.1364/AO.38.003614",
      "volume": "38",
      "year": "1999",
      "journal-title": "Appl. Opt."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/112/13/5942/19296393/5942_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/112/13/5942/19296393/5942_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        7
      ]
    ],
    "date-time": "2024-02-07T14:15:06Z",
    "timestamp": 1707315306000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/112/13/5942/474530/Electron-phonon-coupling-dynamics-in-very-small"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2000,
        4,
        1
      ]
    ]
  },
  "references-count": 42,
  "journal-issue": {
    "issue": "13",
    "published-print": {
      "date-parts": [
        [
          2000,
          4,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.481167",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2000,
        4,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2000,
        4,
        1
      ]
    ]
  }
}