DOI: 10.1063/1.481024. A theory of void formation in charge-stabilized colloidal suspensions at low ionic strength

A theory of void formation in charge-stabilized colloidal suspensions at low ionic strength

10.1063/1.481024

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Using a carefully justified development of Debye–Hückel theory for highly asymmetric electrolytes, one finds that a region of expanded phase instability, or miscibility gap, can appear for charge-stabilized colloidal suspensions at high charges and low ionic strengths. It is argued that this offers a straightforward explanation for the observations of void structures and other anomalies in such suspensions in this region. The nature of the interface between coexisting phases, and general arguments that many-body attractions form a key part of the underlying physical picture, are also examined. The present analysis may also generate new insights into old problems such as coacervation in oppositely charged colloid or protein–polyelectrolyte mixtures, and suggests interesting new possibilities such as the appearance of charge density wave phases in colloidal systems in the vicinity of the critical solution points.

Bibliography

Warren, P. B. (2000). A theory of void formation in charge-stabilized colloidal suspensions at low ionic strength. The Journal of Chemical Physics, 112(10), 4683â4698.

Authors 1

Patrick B. Warren (first)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:19 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 10:56 a.m.)
Indexed	1 month, 2 weeks ago (July 13, 2025, 10:40 p.m.)
Issued	25 years, 5 months ago (March 8, 2000)
Published	25 years, 5 months ago (March 8, 2000)
Published Print	25 years, 5 months ago (March 8, 2000)

Funders 0

None

BibTeX

@article{Warren_2000, title={A theory of void formation in charge-stabilized colloidal suspensions at low ionic strength}, volume={112}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.481024}, DOI={10.1063/1.481024}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Warren, Patrick B.}, year={2000}, month=mar, pages={4683–4698} }

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