DOI: 10.1063/1.479488. Oxygen adsorption on Ag(111): X-ray photoelectron spectroscopy (XPS), angular dependent x-ray photoelectron spectroscopy (ADXPS) and temperature-programmed desorption (TPD) studies

Oxygen adsorption on Ag(111): X-ray photoelectron spectroscopy (XPS), angular dependent x-ray photoelectron spectroscopy (ADXPS) and temperature-programmed desorption (TPD) studies

10.1063/1.479488

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The O2 adsorption on Ag(111) single crystal in the range of 300–500 K has been studied by XPS, ADXPS, and TPD. At room temperature, the O1s line observed at 530.0 eV goes down to 528.2 eV when the sample is heated to 420 K. The comparison of XPS and TPD data indicates that both lines can be assigned to chemisorbed atomic oxygen. The depth concentration profiles calculated on the basis of the angular-dependent XPS data show that the line at 530.0 eV is responsible for oxygen adsorbed at the surface, as opposed to that at 528.2 eV which is assigned to oxygen between the top and second silver layers. The formation of surface silver oxide is concluded in the latter case.

Bibliography

Bukhtiyarov, V. I., Kaichev, V. V., & Prosvirin, I. P. (1999). Oxygen adsorption on Ag(111): X-ray photoelectron spectroscopy (XPS), angular dependent x-ray photoelectron spectroscopy (ADXPS) and temperature-programmed desorption (TPD) studies. The Journal of Chemical Physics, 111(5), 2169â2175.

Authors 3

V. I. Bukhtiyarov (first)
V. V. Kaichev (additional)
I. P. Prosvirin (additional)

References 34 Referenced 87

10.1016/0039-6028(84)90059-1 / Surf. Sci. (1984)
10.1021/j100272a043 / J. Phys. Chem. (1985)
10.1016/0021-9517(85)90270-2 / J. Catal. (1985)
10.1016/0021-9517(86)90341-6 / J. Catal. (1986)
10.1016/S0360-0564(08)60095-4 / Adv. Catal. (1987)
10.1016/0039-6028(84)90557-0 / Surf. Sci. (1984)
10.1016/0039-6028(85)90634-X / Surf. Sci. (1985)
{'key': '2024020522455462500_r8', 'first-page': '619', 'volume': '357–358', 'year': '1996', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1996)
10.1103/PhysRevB.54.2249 / Phys. Rev. B (1996)
10.1016/0039-6028(92)90120-U / Surf. Sci. (1992)
10.1016/0039-6028(95)00482-3 / Surf. Sci. (1995)
10.1016/0009-2614(79)80612-0 / Chem. Phys. Lett. (1979)
10.1016/0039-6028(90)90580-2 / Surf. Sci. (1990)
{'key': '2024020522455462500_r14', 'first-page': '1508', 'volume': '25', 'year': '1984', 'journal-title': 'Kinet. Katal.'} / Kinet. Katal. (1984)
10.1016/0039-6028(82)90194-7 / Surf. Sci. (1982)
10.1016/0368-2048(83)80013-9 / J. Electron Spectrosc. Relat. Phenom. (1983)
10.1016/0039-6028(84)90241-3 / Surf. Sci. (1984)
10.1016/S0039-6028(83)80041-7 / Surf. Sci. (1983)
10.1016/0039-6028(88)90606-1 / Surf. Sci. (1988)
10.1006/jcat.1994.1344 / J. Catal. (1994)
{'key': '2024020522455462500_r21', 'first-page': '493', 'volume': '271', 'year': '1994', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1994)
10.1142/S0218625X94000709 / Surf. Rev. Lett. (1994)
10.1016/0039-6028(74)90229-5 / Surf. Sci. (1974)
10.1016/0039-6028(75)90087-4 / Surf. Sci. (1975)
10.1016/S0039-6028(83)80019-3 / Surf. Sci. (1983)
10.1016/0039-6028(81)90137-0 / Surf. Sci. (1981)
10.1016/0039-6028(90)90056-E / Surf. Sci. (1990)
10.1016/0039-6028(86)90191-3 / Surf. Sci. (1986)
10.1021/ac60363a019 / Anal. Chem. (1975)
{'key': '2024020522455462500_r30', 'first-page': '853', 'volume': '152', 'year': '1963', 'journal-title': 'Dokl. Akad. Nauk SSSR'} / Dokl. Akad. Nauk SSSR (1963)
{'key': '2024020522455462500_r31', 'first-page': '769', 'volume': '299–300', 'year': '1994', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1994)
{'key': '2024020522455462500_r32', 'first-page': '462', 'volume': '55', 'year': '1986', 'journal-title': 'Usp. Khim.'} / Usp. Khim. (1986)
{'key': '2024020522455462500_r33', 'first-page': '1779', 'volume': '79', 'year': '1983', 'journal-title': 'J. Chem. Soc., Faraday Trans. 1'} / J. Chem. Soc., Faraday Trans. 1 (1983)
10.1016/0368-2048(92)85008-U / J. Electron Spectrosc. Relat. Phenom. (1992)

Dates

Type	When
Created	23 years ago (July 26, 2002, 8:17 a.m.)
Deposited	8 months, 2 weeks ago (Dec. 7, 2024, 4:13 p.m.)
Indexed	1 month ago (July 16, 2025, 7:58 a.m.)
Issued	26 years ago (Aug. 1, 1999)
Published	26 years ago (Aug. 1, 1999)
Published Print	26 years ago (Aug. 1, 1999)

Funders 0

None

BibTeX

@article{Bukhtiyarov_1999, title={Oxygen adsorption on Ag(111): X-ray photoelectron spectroscopy (XPS), angular dependent x-ray photoelectron spectroscopy (ADXPS) and temperature-programmed desorption (TPD) studies}, volume={111}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.479488}, DOI={10.1063/1.479488}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bukhtiyarov, V. I. and Kaichev, V. V. and Prosvirin, I. P.}, year={1999}, month=aug, pages={2169–2175} }

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