Abstract
The microscopic diffusional dynamics of H and D on Pt(111) have been studied over length scales between 3 and 14 Å by quasielastic helium atom scattering. Data taken over a wide range of parallel wave vectors (0.3 Å−1⩽|ΔK|⩽3.1 Å−1) in the surface temperature range 140 K⩽Ts⩽250 K and at coverages 0.05 ML⩽ΘH⩽0.66 ML, provide evidence for an isotropic single jump mechanism with an activation energy of 68±5 meV and a pre-exponential factor of D0=1.1±0.5×10−3 cm2 s−1 at low coverages. The diffusion coefficient is 2 to 3 orders of magnitude higher than found in an earlier laser induced desorption experiment, whereas the dependence on coverage is similar.
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Dates
Type | When |
---|---|
Created | 23 years ago (July 26, 2002, 8:17 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 5:05 p.m.) |
Indexed | 1 month, 3 weeks ago (July 2, 2025, 7:30 a.m.) |
Issued | 26 years, 1 month ago (July 22, 1999) |
Published | 26 years, 1 month ago (July 22, 1999) |
Published Print | 26 years, 1 month ago (July 22, 1999) |
@article{Graham_1999, title={Quasielastic helium atom scattering measurements of microscopic diffusional dynamics of H and D on the Pt(111) surface}, volume={111}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.479427}, DOI={10.1063/1.479427}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Graham, Andrew P. and Menzel, Alexander and Toennies, J. Peter}, year={1999}, month=jul, pages={1676–1685} }