Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The microscopic diffusional dynamics of H and D on Pt(111) have been studied over length scales between 3 and 14 Å by quasielastic helium atom scattering. Data taken over a wide range of parallel wave vectors (0.3 Å−1⩽|ΔK|⩽3.1 Å−1) in the surface temperature range 140 K⩽Ts⩽250 K and at coverages 0.05 ML⩽ΘH⩽0.66 ML, provide evidence for an isotropic single jump mechanism with an activation energy of 68±5 meV and a pre-exponential factor of D0=1.1±0.5×10−3 cm2 s−1 at low coverages. The diffusion coefficient is 2 to 3 orders of magnitude higher than found in an earlier laser induced desorption experiment, whereas the dependence on coverage is similar.

Bibliography

Graham, A. P., Menzel, A., & Toennies, J. P. (1999). Quasielastic helium atom scattering measurements of microscopic diffusional dynamics of H and D on the Pt(111) surface. The Journal of Chemical Physics, 111(4), 1676–1685.

Authors 3
  1. Andrew P. Graham (first)
  2. Alexander Menzel (additional)
  3. J. Peter Toennies (additional)
References 65 Referenced 70
  1. 10.1016/0167-5729(88)90009-X / Surf. Sci. Rep. (1988)
  2. 10.1063/1.438041 / J. Chem. Phys. (1979)
  3. 10.1103/PhysRevLett.51.1081 / Phys. Rev. Lett. (1983)
  4. 10.1007/BF02654700 / Metall. Trans. A (1980)
  5. {'key': '2024021022051449400_r5'}
  6. {'key': '2024021022051449400_r6'}
  7. 10.1103/PhysRevB.25.3490 / Phys. Rev. B (1982)
  8. {'key': '2024021022051449400_r8', 'first-page': '4139', 'volume': '83', 'year': '1985', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1985)
  9. 10.1016/0039-6028(91)90010-P / Surf. Sci. (1991)
  10. {'key': '2024021022051449400_r10', 'first-page': '4418', 'volume': '51', 'year': '1995', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1995)
  11. 10.1103/PhysRevLett.79.3696 / Phys. Rev. Lett. (1997)
  12. 10.1063/1.463213 / J. Chem. Phys. (1992)
  13. 10.1103/PhysRevB.51.9985 / Phys. Rev. B (1995)
  14. 10.1088/0034-4885/53/7/002 / Rep. Prog. Phys. (1990)
  15. 10.1002/qua.560350614 / Int. J. Quantum Chem. (1989)
  16. {'key': '2024021022051449400_r16', 'first-page': '90', 'volume': '68', 'year': '1996', 'journal-title': 'Phys. Rev. Lett.'} / Phys. Rev. Lett. (1996)
  17. 10.1016/0009-2614(93)89268-M / Chem. Phys. Lett. (1993)
  18. {'key': '2024021022051449400_r18'}
  19. 10.1021/cr9502209 / Chem. Rev. (1996)
  20. {'key': '2024021022051449400_r20'}
  21. 10.1016/0039-6028(69)90102-2 / Surf. Sci. (1969)
  22. {'key': '2024021022051449400_r22'}
  23. 10.1103/PhysRevB.36.9797 / Phys. Rev. B (1987)
  24. 10.1016/0039-6028(87)90009-4 / Surf. Sci. (1987)
  25. 10.1063/1.472983 / J. Chem. Phys. (1996)
  26. {'key': '2024021022051449400_r26', 'first-page': '546', 'volume': '352–354', 'year': '1996', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1996)
  27. 10.1016/S0039-6028(97)00435-4 / Surf. Sci. (1997)
  28. 10.1103/PhysRevB.56.10567 / Phys. Rev. B (1997)
  29. 10.1209/epl/i1998-00270-x / Europhys. Lett. (1998)
  30. 10.1016/0009-2614(86)87027-0 / Chem. Phys. Lett. (1986)
  31. {'key': '2024021022051449400_r31', 'first-page': '986', 'volume': '53', 'year': '1990', 'journal-title': 'Rep. Prog. Phys.'} / Rep. Prog. Phys. (1990)
  32. {'key': '2024021022051449400_r32', 'first-page': '4977', 'volume': '58', 'year': '1998', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1998)
  33. 10.1016/0375-9601(89)90915-8 / Phys. Lett. A (1989)
  34. 10.1103/PhysRevLett.60.1727 / Phys. Rev. Lett. (1988)
  35. {'key': '2024021022051449400_r35', 'first-page': '938', 'volume': '41', 'year': '1990', 'journal-title': 'Phys. Rev. B'} / Phys. Rev. B (1990)
  36. 10.1103/PhysRev.110.999 / Phys. Rev. (1958)
  37. {'key': '2024021022051449400_r37'}
  38. 10.1088/0370-1328/77/2/319 / Proc. Phys. Soc. London (1961)
  39. 10.1016/0167-5729(85)90007-X / Surf. Sci. Rep. (1985)
  40. {'key': '2024021022051449400_r40'}
  41. {'key': '2024021022051449400_r41', 'first-page': '169', 'volume': '65', 'year': '1977', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1977)
  42. {'key': '2024021022051449400_r42'}
  43. 10.1016/0039-6028(83)90256-X / Surf. Sci. (1983)
  44. 10.1103/PhysRevLett.73.605 / Phys. Rev. Lett. (1994)
  45. 10.1063/1.475240 / J. Chem. Phys. (1997)
  46. {'key': '2024021022051449400_r46'}
  47. {'key': '2024021022051449400_r47'}
  48. 10.1103/PhysRevLett.56.1152 / Phys. Rev. Lett. (1986)
  49. 10.1103/PhysRevB.53.8015 / Phys. Rev. B (1996)
  50. 10.1016/0039-6028(81)90048-0 / Surf. Sci. (1981)
  51. 10.1016/0039-6028(86)90690-4 / Surf. Sci. (1986)
  52. 10.1017/S0305004100019162 / Proc. Cambridge Philos. Soc. (1936)
  53. {'key': '2024021022051449400_r53'}
  54. 10.1142/S0217979297001155 / Int. J. Mod. Phys. B (1997)
  55. {'key': '2024021022051449400_r55'}
  56. {'key': '2024021022051449400_r56'}
  57. {'key': '2024021022051449400_r57'}
  58. 10.1016/0039-6028(79)90082-7 / Surf. Sci. (1979)
  59. 10.1063/1.473231 / J. Chem. Phys. (1997)
  60. 10.1063/1.465645 / J. Chem. Phys. (1993)
  61. {'key': '2024021022051449400_r61', 'first-page': '891', 'volume': '331–333', 'year': '1995', 'journal-title': 'Surf. Sci.'} / Surf. Sci. (1995)
  62. 10.1103/PhysRevB.1.3966 / Phys. Rev. B (1970)
  63. {'key': '2024021022051449400_r63'}
  64. 10.1103/PhysRevLett.42.791 / Phys. Rev. Lett. (1979)
  65. 10.1103/PhysRevLett.66.3164 / Phys. Rev. Lett. (1991)
Dates
Type When
Created 23 years ago (July 26, 2002, 8:17 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 5:05 p.m.)
Indexed 1 month, 3 weeks ago (July 2, 2025, 7:30 a.m.)
Issued 26 years, 1 month ago (July 22, 1999)
Published 26 years, 1 month ago (July 22, 1999)
Published Print 26 years, 1 month ago (July 22, 1999)
Funders 0

None

@article{Graham_1999, title={Quasielastic helium atom scattering measurements of microscopic diffusional dynamics of H and D on the Pt(111) surface}, volume={111}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.479427}, DOI={10.1063/1.479427}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Graham, Andrew P. and Menzel, Alexander and Toennies, J. Peter}, year={1999}, month=jul, pages={1676–1685} }