DOI: 10.1063/1.478986. Adsorption of ethylene on the Ge(100)-2×1 surface: Coverage and time-dependent behavior

Adsorption of ethylene on the Ge(100)-2×1 surface: Coverage and time-dependent behavior

10.1063/1.478986

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Studies of the adsorption and thermal chemistry of ethylene on the Ge(100)-2×1 surface have been performed. The results of multiple internal reflection Fourier transform infrared (MIR-FTIR) spectroscopy and temperature programmed desorption (TPD) show that ethylene chemisorbs molecularly on the Ge(100)-(2×1) surface at room temperature. Infrared spectroscopy gives evidence for only one adsorbate configuration on this surface at room temperature, consistent with a structure in which ethylene bridges across a germanium dimer. However, TPD measurements show two molecular desorption features at almost all coverages, indicating that at least two adsorption states can be formed. Further shifts in one of the peaks with both coverage and time, paralleled by changes in the vibrational spectrum, suggest the presence of attractive intermolecular interactions or cooperative effects. The complex time- and coverage dependence of ethylene adsorption on Ge(100)-2×1 is analyzed using a two-state kinetic model.

Bibliography

Lal, P., Teplyakov, A. V., Noah, Y., Kong, M. J., Wang, G. T., & Bent, S. F. (1999). Adsorption of ethylene on the Ge(100)-2Ã1 surface: Coverage and time-dependent behavior. The Journal of Chemical Physics, 110(21), 10545â10553.

Authors 6

Pratik Lal (first)
Andrew V. Teplyakov (additional)
Yétundé Noah (additional)
Maynard J. Kong (additional)
George T. Wang (additional)
Stacey F. Bent (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:17 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 10:57 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 4:17 a.m.)
Issued	26 years, 3 months ago (June 1, 1999)
Published	26 years, 3 months ago (June 1, 1999)
Published Print	26 years, 3 months ago (June 1, 1999)

Funders 0

None

BibTeX

@article{Lal_1999, title={Adsorption of ethylene on the Ge(100)-2×1 surface: Coverage and time-dependent behavior}, volume={110}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.478986}, DOI={10.1063/1.478986}, number={21}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lal, Pratik and Teplyakov, Andrew V. and Noah, Yétundé and Kong, Maynard J. and Wang, George T. and Bent, Stacey F.}, year={1999}, month=jun, pages={10545–10553} }

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