DOI: 10.1063/1.4776233. Strong coupling between surface plasmon polaritons and β-carotene in nanolayered system

Strong coupling between surface plasmon polaritons and β-carotene in nanolayered system

10.1063/1.4776233

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

In this article we experimentally demonstrate the strong coupling between surface plasmon polaritons (SPP) and the S2 state of β-carotene. The SPPs are excited by prism coupling technique on a thin silver film with β-carotene embedded in a polymer layer on top of that. Rabi splittings with energies 80 and 130 meV are observed in the recorded dispersion relations. Both coupled oscillator model and transfer matrix method are used to fit the experimental results. The scattered radiation of the propagating strongly coupled SPP-S2 hybrids is collected and an increase of the low energy splitting to 120 meV is observed compared to the reflectivity data. In addition, we performed molecule excitation by laser and analyzed the emission patterns revealing clear surface plasmon coupled fluorescence of β-carotene. By increasing the concentration of β-carotene we are able to collect also surface plasmon coupled Raman scattering. This study substantially extends the SPP-molecular excitation strong coupling studies to biomolecules, and energy transfer and coupling properties of excited states of carotenoids.

Bibliography

Baieva, S., Ihalainen, J. A., & Toppari, J. J. (2013). Strong coupling between surface plasmon polaritons and Î²-carotene in nanolayered system. The Journal of Chemical Physics, 138(4).

Authors 3

S. Baieva (first)
J. A. Ihalainen (additional)
J. J. Toppari (additional)

References 52 Referenced 17

10.1103/PhysRevLett.93.036404 / Phys. Rev. Lett. (2004)
10.1103/PhysRevB.71.035424 / Phys. Rev. B (2005)
10.1103/PhysRevLett.103.053602 / Phys. Rev. Lett. (2009)
10.1103/PhysRevLett.98.083001 / Phys. Rev. Lett. (2007)
10.1002/anie.200903191 / Angew. Chem., Int. Ed. (2009)
10.1063/1.3619845 / Appl. Phys. Lett. (2011)
10.1103/PhysRevLett.106.196405 / Phys. Rev. Lett. (2011)
10.1103/PhysRevLett.109.073002 / Phys. Rev. Lett. (2012)
10.1103/PhysRevLett.108.066401 / Phys. Rev. Lett. (2012)
10.1103/PhysRevB.76.035420 / Phys. Rev. B (2007)
10.1038/scientificamerican0407-56 / Sci. Am. (2007)
{'volume-title': 'Plasmonics: Fundamentals and Applications', 'year': '2006', 'key': '2023062523352941200_c12'} / Plasmonics: Fundamentals and Applications (2006)
10.1016/j.physrep.2004.11.001 / Phys. Rep. (2005)
10.1103/PhysRevB.82.035411 / Phys. Rev. B (2010)
10.1364/OL.4.000236 / Opt. Lett. (1979)
10.1080/09500349808230614 / J. Mod. Opt. (1998)
10.1126/science.1102992 / Science (2004)
10.1063/1.1435410 / Appl. Phys. Lett. (2002)
10.1063/1.2987726 / Appl. Phys. Lett. (2008)
10.1002/anie.201006019 / Angew. Chem., Int. Ed. (2011)
10.1146/annurev.anchem.1.031207.112814 / Annu. Rev. Anal. Chem. (2008)
10.1021/j150667a013 / J. Phys. Chem. (1984)
10.1016/S0006-291X(03)01214-2 / Biochem. Biophys. Res. Commun. (2003)
10.1016/j.ab.2003.09.039 / Anal. Biochem. (2004)
10.1016/j.ab.2003.09.036 / Anal. Biochem. (2004)
10.1364/OPEX.13.008855 / Opt. Express (2005)
10.1016/S0956-5663(02)00239-7 / Biosens. Bioelectron. (2003)
10.1021/nl104352j / Nano Lett. (2011)
10.1021/cr020674n / Chem. Rev. (2004)
10.1021/jp9811171 / J. Phys. Chem. B (1998)
10.1039/b514032c / Phys. Chem. Chem. Phys. (2006)
10.1016/j.chemphys.2009.01.001 / Chem. Phys. (2009)
10.1038/nature05678 / Nature (London) (2007)
10.1021/jp0343786 / J. Phys. Chem. B (2003)
10.1063/1.3614543 / Appl. Phys. Lett. (2011)
10.1021/jp980979z / J. Phys. Chem. A (1998)
10.1063/1.444285 / J. Chem. Phys. (1982)
10.1103/PhysRevB.84.205214 / Phys. Rev. B (2011)
10.1002/adfm.201100756 / Adv. Funct. Mater. (2011)
10.1021/jf0634348 / J. Agric. Food Chem. (2007)
10.1021/jf000503o / J. Agric. Food Chem. (2000)
10.1021/jp044847j / J. Phys. Chem. A (2005)
10.1016/S0040-4039(01)00183-6 / Tetrahedron. Lett. (2001)
10.1007/BF00697414 / Appl. Phys. B (1986)
10.1103/PhysRevLett.93.186404 / Phys. Rev. Lett. (2004)
10.1103/PhysRevB.6.4370 / Phys. Rev. B (1972)
10.1186/1556-276X-7-191 / Nanoscale Res. Lett. (2012)
{'first-page': '335', 'volume-title': 'Principles of Nano-Optics', 'year': '2006', 'key': '2023062523352941200_c48'} / Principles of Nano-Optics (2006)
10.1364/JOSAA.22.000190 / J. Opt. Soc. Am. (2005)
10.1063/1.446595 / J. Chem. Phys. (1984)
10.1016/S0379-6779(01)00610-5 / Synth. Met. (2002)
10.1002/jrs.715 / J. Raman Spectrosc. (2001)

Dates

Type	When
Created	12 years, 7 months ago (Jan. 24, 2013, 6:28 p.m.)
Deposited	2 years, 2 months ago (June 25, 2023, 7:35 p.m.)
Indexed	1 month ago (July 30, 2025, 7 a.m.)
Issued	12 years, 7 months ago (Jan. 24, 2013)
Published	12 years, 7 months ago (Jan. 24, 2013)
Published Online	12 years, 7 months ago (Jan. 24, 2013)
Published Print	12 years, 7 months ago (Jan. 28, 2013)

Funders 0

None

BibTeX

@article{Baieva_2013, title={Strong coupling between surface plasmon polaritons and β-carotene in nanolayered system}, volume={138}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.4776233}, DOI={10.1063/1.4776233}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Baieva, S. and Ihalainen, J. A. and Toppari, J. J.}, year={2013}, month=jan }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        30
      ]
    ],
    "date-time": "2025-07-30T11:00:39Z",
    "timestamp": 1753873239606,
    "version": "3.41.2"
  },
  "reference-count": 52,
  "publisher": "AIP Publishing",
  "issue": "4",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2013,
        1,
        28
      ]
    ]
  },
  "abstract": "<jats:p>In this article we experimentally demonstrate the strong coupling between surface plasmon polaritons (SPP) and the S2 state of \u03b2-carotene. The SPPs are excited by prism coupling technique on a thin silver film with \u03b2-carotene embedded in a polymer layer on top of that. Rabi splittings with energies 80 and 130 meV are observed in the recorded dispersion relations. Both coupled oscillator model and transfer matrix method are used to fit the experimental results. The scattered radiation of the propagating strongly coupled SPP-S2 hybrids is collected and an increase of the low energy splitting to 120 meV is observed compared to the reflectivity data. In addition, we performed molecule excitation by laser and analyzed the emission patterns revealing clear surface plasmon coupled fluorescence of \u03b2-carotene. By increasing the concentration of \u03b2-carotene we are able to collect also surface plasmon coupled Raman scattering. This study substantially extends the SPP-molecular excitation strong coupling studies to biomolecules, and energy transfer and coupling properties of excited states of carotenoids.</jats:p>",
  "DOI": "10.1063/1.4776233",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2013,
        1,
        24
      ]
    ],
    "date-time": "2013-01-24T23:28:51Z",
    "timestamp": 1359070131000
  },
  "update-policy": "https://doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 17,
  "title": "Strong coupling between surface plasmon polaritons and \u03b2-carotene in nanolayered system",
  "prefix": "10.1063",
  "volume": "138",
  "author": [
    {
      "given": "S.",
      "family": "Baieva",
      "sequence": "first",
      "affiliation": [
        {
          "name": "University of Jyv\u00e4skyl\u00e4 1 Nanoscience Center, Department of Physics, , Jyv\u00e4skyl\u00e4, P.O. Box 35, FI-40014, Finland"
        }
      ]
    },
    {
      "given": "J. A.",
      "family": "Ihalainen",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "University of Jyv\u00e4skyl\u00e4 2 Nanoscience Center, Department of Biological and Environmental Science, , Jyv\u00e4skyl\u00e4, P.O. Box 35, FI-40014, Finland"
        }
      ]
    },
    {
      "given": "J. J.",
      "family": "Toppari",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "University of Jyv\u00e4skyl\u00e4 1 Nanoscience Center, Department of Physics, , Jyv\u00e4skyl\u00e4, P.O. Box 35, FI-40014, Finland"
        }
      ]
    }
  ],
  "member": "317",
  "published-online": {
    "date-parts": [
      [
        2013,
        1,
        24
      ]
    ]
  },
  "reference": [
    {
      "key": "2023062523352941200_c1",
      "doi-asserted-by": "publisher",
      "first-page": "036404",
      "DOI": "10.1103/PhysRevLett.93.036404",
      "volume": "93",
      "year": "2004",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c2",
      "doi-asserted-by": "publisher",
      "first-page": "035424",
      "DOI": "10.1103/PhysRevB.71.035424",
      "volume": "71",
      "year": "2005",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023062523352941200_c3",
      "doi-asserted-by": "publisher",
      "first-page": "053602",
      "DOI": "10.1103/PhysRevLett.103.053602",
      "volume": "103",
      "year": "2009",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c4",
      "doi-asserted-by": "publisher",
      "first-page": "083001",
      "DOI": "10.1103/PhysRevLett.98.083001",
      "volume": "98",
      "year": "2007",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c5",
      "doi-asserted-by": "publisher",
      "first-page": "8748",
      "DOI": "10.1002/anie.200903191",
      "volume": "48",
      "year": "2009",
      "journal-title": "Angew. Chem., Int. Ed."
    },
    {
      "key": "2023062523352941200_c6",
      "doi-asserted-by": "publisher",
      "first-page": "051110",
      "DOI": "10.1063/1.3619845",
      "volume": "99",
      "year": "2011",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023062523352941200_c7",
      "doi-asserted-by": "publisher",
      "first-page": "196405",
      "DOI": "10.1103/PhysRevLett.106.196405",
      "volume": "106",
      "year": "2011",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c8",
      "doi-asserted-by": "publisher",
      "first-page": "073002",
      "DOI": "10.1103/PhysRevLett.109.073002",
      "volume": "109",
      "year": "2012",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c9",
      "doi-asserted-by": "publisher",
      "first-page": "066401",
      "DOI": "10.1103/PhysRevLett.108.066401",
      "volume": "108",
      "year": "2012",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c10",
      "doi-asserted-by": "publisher",
      "first-page": "035420",
      "DOI": "10.1103/PhysRevB.76.035420",
      "volume": "76",
      "year": "2007",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023062523352941200_c11",
      "doi-asserted-by": "publisher",
      "first-page": "56",
      "DOI": "10.1038/scientificamerican0407-56",
      "volume": "296",
      "year": "2007",
      "journal-title": "Sci. Am."
    },
    {
      "volume-title": "Plasmonics: Fundamentals and Applications",
      "year": "2006",
      "key": "2023062523352941200_c12"
    },
    {
      "key": "2023062523352941200_c13",
      "doi-asserted-by": "publisher",
      "first-page": "131",
      "DOI": "10.1016/j.physrep.2004.11.001",
      "volume": "408",
      "year": "2005",
      "journal-title": "Phys. Rep."
    },
    {
      "key": "2023062523352941200_c14",
      "doi-asserted-by": "publisher",
      "first-page": "035411",
      "DOI": "10.1103/PhysRevB.82.035411",
      "volume": "82",
      "year": "2010",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023062523352941200_c15",
      "doi-asserted-by": "publisher",
      "first-page": "236",
      "DOI": "10.1364/OL.4.000236",
      "volume": "4",
      "year": "1979",
      "journal-title": "Opt. Lett."
    },
    {
      "key": "2023062523352941200_c16",
      "doi-asserted-by": "publisher",
      "first-page": "661",
      "DOI": "10.1080/09500349808230614",
      "volume": "45",
      "year": "1998",
      "journal-title": "J. Mod. Opt."
    },
    {
      "key": "2023062523352941200_c17",
      "doi-asserted-by": "publisher",
      "first-page": "1002",
      "DOI": "10.1126/science.1102992",
      "volume": "306",
      "year": "2004",
      "journal-title": "Science"
    },
    {
      "key": "2023062523352941200_c18",
      "doi-asserted-by": "publisher",
      "first-page": "404",
      "DOI": "10.1063/1.1435410",
      "volume": "80",
      "year": "2002",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023062523352941200_c19",
      "doi-asserted-by": "publisher",
      "first-page": "123307",
      "DOI": "10.1063/1.2987726",
      "volume": "93",
      "year": "2008",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023062523352941200_c20",
      "doi-asserted-by": "publisher",
      "first-page": "2085",
      "DOI": "10.1002/anie.201006019",
      "volume": "50",
      "year": "2011",
      "journal-title": "Angew. Chem., Int. Ed."
    },
    {
      "key": "2023062523352941200_c21",
      "doi-asserted-by": "publisher",
      "first-page": "601",
      "DOI": "10.1146/annurev.anchem.1.031207.112814",
      "volume": "1",
      "year": "2008",
      "journal-title": "Annu. Rev. Anal. Chem."
    },
    {
      "key": "2023062523352941200_c22",
      "doi-asserted-by": "publisher",
      "first-page": "5526",
      "DOI": "10.1021/j150667a013",
      "volume": "88",
      "year": "1984",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2023062523352941200_c23",
      "doi-asserted-by": "publisher",
      "first-page": "435",
      "DOI": "10.1016/S0006-291X(03)01214-2",
      "volume": "307",
      "year": "2003",
      "journal-title": "Biochem. Biophys. Res. Commun."
    },
    {
      "key": "2023062523352941200_c24",
      "doi-asserted-by": "publisher",
      "first-page": "153",
      "DOI": "10.1016/j.ab.2003.09.039",
      "volume": "324",
      "year": "2004",
      "journal-title": "Anal. Biochem."
    },
    {
      "key": "2023062523352941200_c25",
      "doi-asserted-by": "publisher",
      "first-page": "170",
      "DOI": "10.1016/j.ab.2003.09.036",
      "volume": "324",
      "year": "2004",
      "journal-title": "Anal. Biochem."
    },
    {
      "key": "2023062523352941200_c26",
      "doi-asserted-by": "publisher",
      "first-page": "8855",
      "DOI": "10.1364/OPEX.13.008855",
      "volume": "13",
      "year": "2005",
      "journal-title": "Opt. Express"
    },
    {
      "key": "2023062523352941200_c27",
      "doi-asserted-by": "publisher",
      "first-page": "1193",
      "DOI": "10.1016/S0956-5663(02)00239-7",
      "volume": "18",
      "year": "2003",
      "journal-title": "Biosens. Bioelectron."
    },
    {
      "key": "2023062523352941200_c28",
      "doi-asserted-by": "publisher",
      "first-page": "1556",
      "DOI": "10.1021/nl104352j",
      "volume": "11",
      "year": "2011",
      "journal-title": "Nano Lett."
    },
    {
      "key": "2023062523352941200_c29",
      "doi-asserted-by": "publisher",
      "first-page": "2021",
      "DOI": "10.1021/cr020674n",
      "volume": "104",
      "year": "2004",
      "journal-title": "Chem. Rev."
    },
    {
      "key": "2023062523352941200_c30",
      "doi-asserted-by": "publisher",
      "first-page": "5378",
      "DOI": "10.1021/jp9811171",
      "volume": "102",
      "year": "1998",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2023062523352941200_c31",
      "doi-asserted-by": "publisher",
      "first-page": "793",
      "DOI": "10.1039/b514032c",
      "volume": "8",
      "year": "2006",
      "journal-title": "Phys. Chem. Chem. Phys."
    },
    {
      "key": "2023062523352941200_c32",
      "doi-asserted-by": "publisher",
      "first-page": "171",
      "DOI": "10.1016/j.chemphys.2009.01.001",
      "volume": "357",
      "year": "2009",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2023062523352941200_c33",
      "doi-asserted-by": "publisher",
      "first-page": "782",
      "DOI": "10.1038/nature05678",
      "volume": "446",
      "year": "2007",
      "journal-title": "Nature (London)"
    },
    {
      "key": "2023062523352941200_c34",
      "doi-asserted-by": "publisher",
      "first-page": "6162",
      "DOI": "10.1021/jp0343786",
      "volume": "107",
      "year": "2003",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "2023062523352941200_c35",
      "doi-asserted-by": "publisher",
      "first-page": "031105",
      "DOI": "10.1063/1.3614543",
      "volume": "99",
      "year": "2011",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2023062523352941200_c36",
      "doi-asserted-by": "publisher",
      "first-page": "5049",
      "DOI": "10.1021/jp980979z",
      "volume": "102",
      "year": "1998",
      "journal-title": "J. Phys. Chem. A"
    },
    {
      "key": "2023062523352941200_c37",
      "doi-asserted-by": "publisher",
      "first-page": "3414",
      "DOI": "10.1063/1.444285",
      "volume": "77",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2023062523352941200_c38",
      "doi-asserted-by": "publisher",
      "first-page": "205214",
      "DOI": "10.1103/PhysRevB.84.205214",
      "volume": "84",
      "year": "2011",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023062523352941200_c39",
      "doi-asserted-by": "publisher",
      "first-page": "3691",
      "DOI": "10.1002/adfm.201100756",
      "volume": "21",
      "year": "2011",
      "journal-title": "Adv. Funct. Mater."
    },
    {
      "key": "2023062523352941200_c40",
      "doi-asserted-by": "publisher",
      "first-page": "5238",
      "DOI": "10.1021/jf0634348",
      "volume": "55",
      "year": "2007",
      "journal-title": "J. Agric. Food Chem."
    },
    {
      "key": "2023062523352941200_c41",
      "doi-asserted-by": "publisher",
      "first-page": "5008",
      "DOI": "10.1021/jf000503o",
      "volume": "48",
      "year": "2000",
      "journal-title": "J. Agric. Food Chem."
    },
    {
      "key": "2023062523352941200_c42",
      "doi-asserted-by": "publisher",
      "first-page": "1521",
      "DOI": "10.1021/jp044847j",
      "volume": "109",
      "year": "2005",
      "journal-title": "J. Phys. Chem. A"
    },
    {
      "key": "2023062523352941200_c43",
      "doi-asserted-by": "publisher",
      "first-page": "2561",
      "DOI": "10.1016/S0040-4039(01)00183-6",
      "volume": "42",
      "year": "2001",
      "journal-title": "Tetrahedron. Lett."
    },
    {
      "key": "2023062523352941200_c44",
      "doi-asserted-by": "publisher",
      "first-page": "165",
      "DOI": "10.1007/BF00697414",
      "volume": "39",
      "year": "1986",
      "journal-title": "Appl. Phys. B"
    },
    {
      "key": "2023062523352941200_c45",
      "doi-asserted-by": "publisher",
      "first-page": "186404",
      "DOI": "10.1103/PhysRevLett.93.186404",
      "volume": "93",
      "year": "2004",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2023062523352941200_c46",
      "doi-asserted-by": "publisher",
      "first-page": "4370",
      "DOI": "10.1103/PhysRevB.6.4370",
      "volume": "6",
      "year": "1972",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2023062523352941200_c47",
      "doi-asserted-by": "publisher",
      "first-page": "191",
      "DOI": "10.1186/1556-276X-7-191",
      "volume": "7",
      "year": "2012",
      "journal-title": "Nanoscale Res. Lett."
    },
    {
      "first-page": "335",
      "volume-title": "Principles of Nano-Optics",
      "year": "2006",
      "key": "2023062523352941200_c48"
    },
    {
      "key": "2023062523352941200_c49",
      "doi-asserted-by": "publisher",
      "first-page": "190",
      "DOI": "10.1364/JOSAA.22.000190",
      "volume": "22",
      "year": "2005",
      "journal-title": "J. Opt. Soc. Am."
    },
    {
      "key": "2023062523352941200_c50",
      "doi-asserted-by": "publisher",
      "first-page": "5245",
      "DOI": "10.1063/1.446595",
      "volume": "80",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2023062523352941200_c51",
      "doi-asserted-by": "publisher",
      "first-page": "151",
      "DOI": "10.1016/S0379-6779(01)00610-5",
      "volume": "127",
      "year": "2002",
      "journal-title": "Synth. Met."
    },
    {
      "key": "2023062523352941200_c52",
      "doi-asserted-by": "publisher",
      "first-page": "543",
      "DOI": "10.1002/jrs.715",
      "volume": "32",
      "year": "2001",
      "journal-title": "J. Raman Spectrosc."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.4776233/15461738/044707_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.4776233/15461738/044707_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        6,
        25
      ]
    ],
    "date-time": "2023-06-25T23:35:34Z",
    "timestamp": 1687736134000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/138/4/044707/193252/Strong-coupling-between-surface-plasmon-polaritons"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2013,
        1,
        24
      ]
    ]
  },
  "references-count": 52,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          2013,
          1,
          28
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.4776233",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        2013,
        1,
        28
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        2013,
        1,
        24
      ]
    ]
  },
  "article-number": "044707"
}