DOI: 10.1063/1.477613. Screening and asymptotic decay of pair distributions in asymmetric electrolytes

Screening and asymptotic decay of pair distributions in asymmetric electrolytes

10.1063/1.477613

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

An accurate description of the screening behavior of asymmetric binary electrolyte solutions is obtained by applying the dressed ion theory to acquire the three leading terms in the asymptotic decay of the radial pair distribution function gij(r) at large distances r. These terms give a surprisingly good representation of the distribution function for quite small r values. A minimum of two asymptotic terms are needed for representing gij(r) at moderately large r in a quite wide concentration range. The relationships between the large r asymptotic behavior of charge–charge, density–density, and charge–density correlations are investigated by means of the dressed ion distribution functions. The role that the dielectric response function of the electrolyte plays for the asymptotic behavior is illuminated and the relationship between this function and the dressed ion charge distributions is given. Ionic effective charges, effective permittivities, and decay lengths and their higher order analogues are calculated for 1:2 electrolytes using the hypernetted chain approximation.

Bibliography

Ulander, J., & Kjellander, R. (1998). Screening and asymptotic decay of pair distributions in asymmetric electrolytes. The Journal of Chemical Physics, 109(21), 9508â9522.

Authors 2

Johan Ulander (first)
Roland Kjellander (additional)

References 32 Referenced 36

{'key': '2024020712323570300_r1', 'first-page': '185', 'volume': '24', 'year': '1923', 'journal-title': 'Phys. Z.'} / Phys. Z. (1923)
10.1021/cr60064a007 / Chem. Rev. (1936)
10.1021/j150518a004 / J. Phys. Chem. (1954)
10.1063/1.1731401 / J. Chem. Phys. (1960)
10.1063/1.1669710 / J. Chem. Phys. (1968)
10.1063/1.1670656 / J. Chem. Phys. (1968)
10.1063/1.1669709 / J. Chem. Phys. (1968)
10.1063/1.1669710 / J. Chem. Phys. (1968)
10.1063/1.1670358 / J. Chem. Phys. (1968)
10.1016/0009-2614(70)80006-9 / Chem. Phys. Lett. (1970)
10.1016/0009-2614(70)80303-7 / Chem. Phys. Lett. (1970)
10.1063/1.1676854 / J. Chem. Phys. (1972)
{'key': '2024020712323570300_r12', 'first-page': '109', 'volume': '40A', 'year': '1972', 'journal-title': 'Phys. Lett.'} / Phys. Lett. (1972)
10.1063/1.1678512 / J. Chem. Phys. (1972)
10.1063/1.1678973 / J. Chem. Phys. (1973)
{'key': '2024020712323570300_r15'}
10.1021/j100528a019 / J. Phys. Chem. (1977)
10.1063/1.463491 / J. Chem. Phys. (1992)
{'key': '2024020712323570300_r18'}
10.1080/00268979600100711 / Mol. Phys. (1996)
10.1103/PhysRev.174.280 / Phys. Rev. (1968)
10.1016/0009-2614(78)85426-8 / Chem. Phys. Lett. (1978)
10.1016/0009-2614(92)87048-T / Chem. Phys. Lett. (1992)
10.1063/1.468116 / J. Chem. Phys. (1994)
10.1039/f29736901391 / J. Chem. Soc., Faraday Trans. 2 (1973)
{'key': '2024020712323570300_r25'}
10.1063/1.469166 / J. Chem. Phys. (1995)
10.1080/00268979400101491 / Mol. Phys. (1994)
10.1103/PhysRevE.48.3604 / Phys. Rev. E (1993)
{'key': '2024020712323570300_r29'}
10.1063/1.476810 / J. Chem. Phys. (1998)
{'key': '2024020712323570300_r31'}

Dates

Type	When
Created	23 years ago (July 26, 2002, 8:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 2:09 p.m.)
Indexed	4 months, 2 weeks ago (April 5, 2025, 1:49 a.m.)
Issued	26 years, 8 months ago (Dec. 1, 1998)
Published	26 years, 8 months ago (Dec. 1, 1998)
Published Print	26 years, 8 months ago (Dec. 1, 1998)

Funders 0

None

BibTeX

@article{Ulander_1998, title={Screening and asymptotic decay of pair distributions in asymmetric electrolytes}, volume={109}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.477613}, DOI={10.1063/1.477613}, number={21}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ulander, Johan and Kjellander, Roland}, year={1998}, month=dec, pages={9508–9522} }

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