DOI: 10.1063/1.477374. Infrared spectroscopy analysis of the local atomic structure in silica prepared by sol-gel

Infrared spectroscopy analysis of the local atomic structure in silica prepared by sol-gel

10.1063/1.477374

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Infrared spectroscopy has been used to analyze the structural changes in samples prepared by the sol-gel method. Silica gels were prepared from alcoholic solutions of tetraethylorthosilicate (TEOS) with different H2O/TEOS molar ratios. The IR spectra of these gels, in the Si–O bond stretching region, shows that their structure strongly depends on the H2O/TEOS ratio. The relative change in intensity of the Si–O stretching modes, in samples prepared using different H2O/TEOS ratios, are interpreted in terms of different degrees of structural disorder. According to our infrared absorption data, a decrease in the H2O/TEOS ratio from about 7, the SiO2 structure evolves from a three-dimensional network toward a chainlike structure.

Bibliography

MartÄ±Ìnez, J. R., Ruiz, F., Vorobiev, Y. V., PÃ©rez-Robles, F., & GonzÃ¡lez-HernÃ¡ndez, J. (1998). Infrared spectroscopy analysis of the local atomic structure in silica prepared by sol-gel. The Journal of Chemical Physics, 109(17), 7511â7514.

Authors 5

J. R. Martı́nez (first)
F. Ruiz (additional)
Y. V. Vorobiev (additional)
F. Pérez-Robles (additional)
J. González-Hernández (additional)

References 23 Referenced 144

{'key': '2024021020251860300_r1'}
10.1016/0022-3093(88)90308-0 / J. Non-Cryst. Solids (1988)
{'key': '2024021020251860300_r3', 'first-page': '51', 'volume': '82', 'year': '1988', 'journal-title': 'J. Non-Cryst. Solids'} / J. Non-Cryst. Solids (1988)
10.1038/2121353a0 / Nature (London) (1966)
10.1063/1.1677474 / J. Chem. Phys. (1972)
10.1111/j.1151-2916.1970.tb12012.x / J. Am. Ceram. Soc. (1970)
10.1088/0022-3719/9/7/008 / J. Phys. C (1976)
10.1088/0022-3719/3/10/013 / J. Phys. C (1970)
10.1103/PhysRevB.15.4030 / Phys. Rev. B (1977)
10.1103/PhysRevB.16.2942 / Phys. Rev. B (1977)
10.1080/13642817908246002 / Philos. Mag. B (1979)
{'key': '2024021020251860300_r12'}
10.1063/1.98408 / Appl. Phys. Lett. (1987)
10.1063/1.344472 / J. Appl. Phys. (1989)
10.1103/PhysRevB.38.1255 / Phys. Rev. B (1988)
10.1016/0022-3093(72)90305-5 / J. Non-Cryst. Solids (1972)
10.1016/0022-3093(82)90244-7 / J. Non-Cryst. Solids (1982)
10.1016/0022-3093(86)90112-2 / J. Non-Cryst. Solids (1986)
10.1016/0022-3093(82)90245-9 / J. Non-Cryst. Solids (1982)
10.1016/0022-3093(84)90385-5 / J. Non-Cryst. Solids (1984)
10.1016/0022-3093(85)90103-6 / J. Non-Cryst. Solids (1985)
{'key': '2024021020251860300_r22', 'first-page': '87', 'volume': '38', 'year': '1980', 'journal-title': 'J. Non-Cryst. Solids'} / J. Non-Cryst. Solids (1980)
{'key': '2024021020251860300_r23', 'first-page': '3359', 'volume': '19', 'year': '1998', 'journal-title': 'Proc. SPIE'} / Proc. SPIE (1998)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 3:25 p.m.)
Indexed	1 month, 3 weeks ago (July 7, 2025, 9:06 a.m.)
Issued	26 years, 10 months ago (Nov. 1, 1998)
Published	26 years, 10 months ago (Nov. 1, 1998)
Published Print	26 years, 10 months ago (Nov. 1, 1998)

Funders 0

None

BibTeX

@article{Mart_nez_1998, title={Infrared spectroscopy analysis of the local atomic structure in silica prepared by sol-gel}, volume={109}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.477374}, DOI={10.1063/1.477374}, number={17}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Martı́nez, J. R. and Ruiz, F. and Vorobiev, Y. V. and Pérez-Robles, F. and González-Hernández, J.}, year={1998}, month=nov, pages={7511–7514} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        7
      ]
    ],
    "date-time": "2025-07-07T13:06:29Z",
    "timestamp": 1751893589606
  },
  "reference-count": 23,
  "publisher": "AIP Publishing",
  "issue": "17",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1998,
        11,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Infrared spectroscopy has been used to analyze the structural changes in samples prepared by the sol-gel method. Silica gels were prepared from alcoholic solutions of tetraethylorthosilicate (TEOS) with different H2O/TEOS molar ratios. The IR spectra of these gels, in the Si\u2013O bond stretching region, shows that their structure strongly depends on the H2O/TEOS ratio. The relative change in intensity of the Si\u2013O stretching modes, in samples prepared using different H2O/TEOS ratios, are interpreted in terms of different degrees of structural disorder. According to our infrared absorption data, a decrease in the H2O/TEOS ratio from about 7, the SiO2 structure evolves from a three-dimensional network toward a chainlike structure.</jats:p>",
  "DOI": "10.1063/1.477374",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T12:16:49Z",
    "timestamp": 1027685809000
  },
  "page": "7511-7514",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 144,
  "title": "Infrared spectroscopy analysis of the local atomic structure in silica prepared by sol-gel",
  "prefix": "10.1063",
  "volume": "109",
  "author": [
    {
      "given": "J. R.",
      "family": "Mart\u0131\u0301nez",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Facultad de Ciencias, Universidad Aut\u00f3noma de San Luis Potos\u0131\u0301, 78000\u2009San Luis Potos\u0131\u0301, S.L.P., M\u00e9xico"
        }
      ]
    },
    {
      "given": "F.",
      "family": "Ruiz",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de F\u0131\u0301sica \u201cManuel Sandoval Vallarta,\u201d Universidad Aut\u00f3noma de San Luis Potos\u0131\u0301\u200978000, San Luis Potos\u0131\u0301, S.L.P., M\u00e9xico"
        }
      ]
    },
    {
      "given": "Y. V.",
      "family": "Vorobiev",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratorio de Investigaci\u00f3n en Materiales, Centro de Investigaci\u00f3n y de Estudios Avanzados del IPN, Facultad de Qu\u0131\u0301mica, Universidad Aut\u00f3noma de Quer\u00e9taro, Cerro de las Campanas s/n, 76010\u2009Quer\u00e9taro, Qro., M\u00e9xico"
        }
      ]
    },
    {
      "given": "F.",
      "family": "P\u00e9rez-Robles",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratorio de Investigaci\u00f3n en Materiales, Centro de Investigaci\u00f3n y de Estudios Avanzados del IPN, Facultad de Qu\u0131\u0301mica, Universidad Aut\u00f3noma de Quer\u00e9taro, Cerro de las Campanas s/n, 76010\u2009Quer\u00e9taro, Qro., M\u00e9xico"
        }
      ]
    },
    {
      "given": "J.",
      "family": "Gonz\u00e1lez-Hern\u00e1ndez",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratorio de Investigaci\u00f3n en Materiales, Centro de Investigaci\u00f3n y de Estudios Avanzados del IPN, Facultad de Qu\u0131\u0301mica, Universidad Aut\u00f3noma de Quer\u00e9taro, Cerro de las Campanas s/n, 76010\u2009Quer\u00e9taro, Qro., M\u00e9xico"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021020251860300_r1"
    },
    {
      "key": "2024021020251860300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "201",
      "DOI": "10.1016/0022-3093(88)90308-0",
      "volume": "105",
      "year": "1988",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r3",
      "first-page": "51",
      "volume": "82",
      "year": "1988",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r4",
      "doi-asserted-by": "crossref",
      "first-page": "1353",
      "DOI": "10.1038/2121353a0",
      "volume": "212",
      "year": "1966",
      "journal-title": "Nature (London)"
    },
    {
      "key": "2024021020251860300_r5",
      "doi-asserted-by": "crossref",
      "first-page": "1910",
      "DOI": "10.1063/1.1677474",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021020251860300_r6",
      "doi-asserted-by": "crossref",
      "first-page": "69",
      "DOI": "10.1111/j.1151-2916.1970.tb12012.x",
      "volume": "53",
      "year": "1970",
      "journal-title": "J. Am. Ceram. Soc."
    },
    {
      "key": "2024021020251860300_r7",
      "doi-asserted-by": "crossref",
      "first-page": "1171",
      "DOI": "10.1088/0022-3719/9/7/008",
      "volume": "9",
      "year": "1976",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "2024021020251860300_r8",
      "doi-asserted-by": "crossref",
      "first-page": "2111",
      "DOI": "10.1088/0022-3719/3/10/013",
      "volume": "3",
      "year": "1970",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "2024021020251860300_r9",
      "doi-asserted-by": "crossref",
      "first-page": "4030",
      "DOI": "10.1103/PhysRevB.15.4030",
      "volume": "15",
      "year": "1977",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024021020251860300_r10",
      "doi-asserted-by": "crossref",
      "first-page": "2942",
      "DOI": "10.1103/PhysRevB.16.2942",
      "volume": "16",
      "year": "1977",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024021020251860300_r11",
      "doi-asserted-by": "crossref",
      "first-page": "513",
      "DOI": "10.1080/13642817908246002",
      "volume": "39",
      "year": "1979",
      "journal-title": "Philos. Mag. B"
    },
    {
      "key": "2024021020251860300_r12"
    },
    {
      "key": "2024021020251860300_r13",
      "doi-asserted-by": "crossref",
      "first-page": "418",
      "DOI": "10.1063/1.98408",
      "volume": "51",
      "year": "1987",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "2024021020251860300_r14",
      "doi-asserted-by": "crossref",
      "first-page": "201",
      "DOI": "10.1063/1.344472",
      "volume": "66",
      "year": "1989",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "2024021020251860300_r15",
      "doi-asserted-by": "crossref",
      "first-page": "1255",
      "DOI": "10.1103/PhysRevB.38.1255",
      "volume": "38",
      "year": "1988",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "2024021020251860300_r16",
      "doi-asserted-by": "crossref",
      "first-page": "25",
      "DOI": "10.1016/0022-3093(72)90305-5",
      "volume": "11",
      "year": "1972",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r17",
      "doi-asserted-by": "crossref",
      "first-page": "31",
      "DOI": "10.1016/0022-3093(82)90244-7",
      "volume": "48",
      "year": "1982",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r18",
      "doi-asserted-by": "crossref",
      "first-page": "69",
      "DOI": "10.1016/0022-3093(86)90112-2",
      "volume": "82",
      "year": "1986",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r19",
      "doi-asserted-by": "crossref",
      "first-page": "47",
      "DOI": "10.1016/0022-3093(82)90245-9",
      "volume": "48",
      "year": "1982",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r20",
      "doi-asserted-by": "crossref",
      "first-page": "45",
      "DOI": "10.1016/0022-3093(84)90385-5",
      "volume": "63",
      "year": "1984",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r21",
      "doi-asserted-by": "crossref",
      "first-page": "301",
      "DOI": "10.1016/0022-3093(85)90103-6",
      "volume": "70",
      "year": "1985",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r22",
      "first-page": "87",
      "volume": "38",
      "year": "1980",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024021020251860300_r23",
      "first-page": "3359",
      "volume": "19",
      "year": "1998",
      "journal-title": "Proc. SPIE"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/109/17/7511/19031665/7511_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/109/17/7511/19031665/7511_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T20:25:45Z",
    "timestamp": 1707596745000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/109/17/7511/476732/Infrared-spectroscopy-analysis-of-the-local-atomic"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1998,
        11,
        1
      ]
    ]
  },
  "references-count": 23,
  "journal-issue": {
    "issue": "17",
    "published-print": {
      "date-parts": [
        [
          1998,
          11,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.477374",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1998,
        11,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1998,
        11,
        1
      ]
    ]
  }
}