DOI: 10.1063/1.475698. Structure and phase diagram of mixtures of hard spheres in the limit of infinite size ratio

Structure and phase diagram of mixtures of hard spheres in the limit of infinite size ratio

10.1063/1.475698

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The phase diagram of a mixture of hard spheres for the particular case of infinite size ratio is considered. This is equivalent to the problem of a mixture of points and hard spheres, with the condition that the points can not penetrate the spheres. The equation of state and free energy of this system can be related to that of a pure hard sphere system. This is true for the fluid and for the solid phase. In this way it is shown that in the limit of infinite size ratio, no fluid-fluid separation is possible for binary mixtures of hard spheres and that freezing occurs at the same volume fraction than for pure hard spheres.

Bibliography

Vega, C. (1998). Structure and phase diagram of mixtures of hard spheres in the limit of infinite size ratio. The Journal of Chemical Physics, 108(7), 3074â3075.

Authors 1

Carlos Vega (first)

References 19 Referenced 15

10.1080/00268979100100501 / Mol. Phys. (1991)
10.1080/00268979300101101 / Mol. Phys. (1993)
10.1016/0378-3812(95)02944-3 / Fluid Phase Equilibria (1996)
10.1103/PhysRevLett.66.2215 / Phys. Rev. Lett. (1991)
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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 12:39 a.m.)
Indexed	1 year, 5 months ago (March 15, 2024, 1:11 p.m.)
Issued	27 years, 6 months ago (Feb. 15, 1998)
Published	27 years, 6 months ago (Feb. 15, 1998)
Published Print	27 years, 6 months ago (Feb. 15, 1998)

Funders 0

None

BibTeX

@article{Vega_1998, title={Structure and phase diagram of mixtures of hard spheres in the limit of infinite size ratio}, volume={108}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.475698}, DOI={10.1063/1.475698}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Vega, Carlos}, year={1998}, month=feb, pages={3074–3075} }

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