DOI: 10.1063/1.475452. A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl

A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl

10.1063/1.475452

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Using deuteron NMR techniques two-, effective three-, and various four-time correlation functions were recorded for supercooled ortho-terphenyl at 10–15 K above the calorimetric glass transition in order to characterize the heterogeneous nature of its primary response. The experimental results could successfully be described within various energy landscape models as well as via continuous time random walk simulations. These theoretical considerations provide a suitable basis for a definition of the term dynamic heterogeneity. We discuss the power but also some limitations of the present multidimensional NMR techniques when applied to amorphous materials.

Bibliography

BÃ¶hmer, R., Diezemann, G., Hinze, G., & Sillescu, H. (1998). A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl. The Journal of Chemical Physics, 108(3), 890â899.

Authors 4

R. Böhmer (first)
G. Diezemann (additional)
G. Hinze (additional)
H. Sillescu (additional)

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:16 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 6:13 p.m.)
Indexed	1 year ago (Aug. 7, 2024, 11:09 a.m.)
Issued	27 years, 7 months ago (Jan. 15, 1998)
Published	27 years, 7 months ago (Jan. 15, 1998)
Published Print	27 years, 7 months ago (Jan. 15, 1998)

Funders 0

None

BibTeX

@article{B_hmer_1998, title={A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl}, volume={108}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.475452}, DOI={10.1063/1.475452}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Böhmer, R. and Diezemann, G. and Hinze, G. and Sillescu, H.}, year={1998}, month=jan, pages={890–899} }

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