DOI: 10.1063/1.474715. Photoelectron spectroscopy of C4−, C6−, and C8−

Photoelectron spectroscopy of C4−, C6−, and C8−

10.1063/1.474715

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Photoelectron spectra of C4−, C6−, and C8− were obtained at two photodetachment wavelengths, 266 nm (4.657 eV) and 213 nm (5.822 eV). The spectra reveal considerably more electronic and vibrational structure than was seen in previous studies of these species [D. W. Arnold et al., J. Chem. Phys. 95, 8753 (1991)]. Term values for several low-lying excited electronic states of the neutral carbon clusters have been obtained, as well as new vibrational frequencies for the ground and some of the excited electronic states of the neutral clusters. The assignments of excited electronic states were aided by measurements of the photoelectron angular distributions. A new assignment of the vibrational frequencies for C6 is in considerably better agreement with ab initio results than our original assignment.

Bibliography

Xu, C., Burton, G. R., Taylor, T. R., & Neumark, D. M. (1997). Photoelectron spectroscopy of C4â, C6â, and C8â. The Journal of Chemical Physics, 107(9), 3428â3436.

Authors 4

Cangshan Xu (first)
Gordon R. Burton (additional)
Travis R. Taylor (additional)
Daniel M. Neumark (additional)

References 49 Referenced 92

10.1021/cr00098a005 / Chem. Rev. (1989)
10.1016/0009-2614(89)87196-9 / Chem. Phys. Lett. (1989)
10.1063/1.457073 / J. Chem. Phys. (1989)
10.1126/science.244.4904.562 / Science (1989)
10.1063/1.459797 / J. Chem. Phys. (1991)
10.1080/00268979300101611 / Mol. Phys. (1993)
{'key': '2024020519283625800_r7'}
10.1126/science.11539187 / Science (1994)
{'key': '2024020519283625800_r9', 'first-page': '8753', 'volume': '95', 'year': '1991', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1991)
10.1063/1.463722 / J. Chem. Phys. (1992)
10.1063/1.465340 / J. Chem. Phys. (1993)
10.1038/269130a0 / Nature (1977)
10.1063/1.469620 / J. Chem. Phys. (1995)
10.1063/1.471127 / J. Chem. Phys. (1996)
10.1063/1.469621 / J. Chem. Phys. (1995)
10.1063/1.450259 / J. Chem. Phys. (1986)
10.1016/0009-2614(90)85180-K / Chem. Phys. Lett. (1990)
10.1063/1.460100 / J. Chem. Phys. (1991)
10.1063/1.454276 / J. Chem. Phys. (1988)
10.1016/0301-0104(91)89007-W / Chem. Phys. (1991)
10.1063/1.457186 / J. Chem. Phys. (1989)
10.1016/0009-2614(87)80548-1 / Chem. Phys. Lett. (1987)
10.1016/0009-2614(88)87291-9 / Chem. Phys. Lett. (1988)
10.1063/1.465339 / J. Chem. Phys. (1993)
10.1016/0009-2614(95)00081-E / Chem. Phys. Lett. (1995)
10.1021/j100367a034 / J. Phys. Chem. (1990)
10.1063/1.471132 / J. Chem. Phys. (1996)
10.1063/1.1143294 / Rev. Sci. Instrum. (1992)
{'key': '2024020519283625800_r29', 'first-page': '9416', 'volume': '95', 'year': '1991', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1991)
{'key': '2024020519283625800_r30', 'first-page': '1498', 'volume': '41', 'year': '1971', 'journal-title': 'Zh. Tekh. Fiz.'} / Zh. Tekh. Fiz. (1971)
{'key': '2024020519283625800_r31', 'first-page': '82', 'volume': '64', 'year': '1973', 'journal-title': 'Zh. Eksp. Teor. Fiz.'} / Zh. Eksp. Teor. Fiz. (1973)
10.1063/1.1715212 / Rev. Sci. Instrum. (1955)
{'key': '2024020519283625800_r33', 'first-page': '1500', 'volume': '76', 'year': '1979', 'journal-title': 'Zh. Eksp. Teor. Fiz.'} / Zh. Eksp. Teor. Fiz. (1979)
{'key': '2024020519283625800_r34'}
{'key': '2024020519283625800_r35'}
10.1016/0009-2614(91)87066-K / Chem. Phys. Lett. (1991)
10.1016/0009-2614(91)80101-3 / Chem. Phys. Lett. (1991)
10.1063/1.462980 / J. Chem. Phys. (1992)
10.1063/1.432404 / J. Chem. Phys. (1976)
10.1063/1.1668742 / J. Chem. Phys. (1968)
{'key': '2024020519283625800_r41'}
10.1086/169862 / Astrophys. J. (1991)
10.1002/jcc.540120107 / J. Comput. Chem. (1991)
10.1063/1.459747 / J. Chem. Phys. (1991)
10.1063/1.468149 / J. Chem. Phys. (1994)
{'key': '2024020519283625800_r46', 'first-page': '621', 'volume': '150', 'year': '1995', 'journal-title': 'Int. J. Mass. Spec. Ion. Proc.'} / Int. J. Mass. Spec. Ion. Proc. (1995)
10.1063/1.459224 / J. Chem. Phys. (1990)
10.1021/ja00081a041 / J. Am. Chem. Soc. (1994)
10.1016/0009-2614(95)00989-H / Chem. Phys. Lett. (1995)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:25 a.m.)
Deposited	1 year, 6 months ago (Feb. 5, 2024, 3:34 p.m.)
Indexed	11 months, 3 weeks ago (Sept. 12, 2024, 3:56 p.m.)
Issued	28 years ago (Sept. 1, 1997)
Published	28 years ago (Sept. 1, 1997)
Published Print	28 years ago (Sept. 1, 1997)

Funders 0

None

BibTeX

@article{Xu_1997, title={Photoelectron spectroscopy of C4−, C6−, and C8−}, volume={107}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.474715}, DOI={10.1063/1.474715}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Xu, Cangshan and Burton, Gordon R. and Taylor, Travis R. and Neumark, Daniel M.}, year={1997}, month=sep, pages={3428–3436} }

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      "key": "2024020519283625800_r27",
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      "first-page": "5026",
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      "first-page": "1840",
      "DOI": "10.1063/1.1143294",
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      "journal-title": "Rev. Sci. Instrum."
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    {
      "key": "2024020519283625800_r29",
      "first-page": "9416",
      "volume": "95",
      "year": "1991",
      "journal-title": "J. Chem. Phys."
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      "volume": "41",
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      "journal-title": "Zh. Tekh. Fiz."
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      "key": "2024020519283625800_r31",
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      "key": "2024020519283625800_r33",
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      "URL": "https://pubs.aip.org/jcp/article/107/9/3428/477809/Photoelectron-spectroscopy-of-C4-C6-and-C8"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1997,
        9,
        1
      ]
    ]
  },
  "references-count": 49,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          1997,
          9,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.474715",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1997,
        9,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1997,
        9,
        1
      ]
    ]
  }
}