DOI: 10.1063/1.474456. Dynamics of glass-forming liquids. III. Comparing the dielectric α- and β-relaxation of 1-propanol and o-terphenyl

Dynamics of glass-forming liquids. III. Comparing the dielectric α- and β-relaxation of 1-propanol and o-terphenyl

10.1063/1.474456

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We have measured the dielectric relaxation of the glass-former 1-propanol for temperatures between 65 and 350 K in the frequency range 10−2 to 2⋅1010 Hz and the photon correlation spectro-scopy decays near Tg. Attributing the strong Debye-type process of 1-propanol to distinct -OH group effects leaves two faster processes related to the structural relaxation which can be identified as α-relaxation and Johari–Goldstein type β-relaxation characteristic of nonhydrogen-bonding supercooled liquids. From the temperature dependent relaxation times τ(T) regarding the three distinct loss peaks, we can specify an α-β-bifurcation temperature Tβ, which coincides with characteristic qualitative changes in the τ(T) behavior, as also observed for ortho-terphenyl and other glass-forming liquids. This assignment is confirmed by the correla-tion times derived from incoherent quasielastic light-scattering data obtained from the simultaneously measured photon-correlation spectroscopy.

Bibliography

Hansen, C., Stickel, F., Berger, T., Richert, R., & Fischer, E. W. (1997). Dynamics of glass-forming liquids. III. Comparing the dielectric Î±- and Î²-relaxation of 1-propanol and o-terphenyl. The Journal of Chemical Physics, 107(4), 1086â1093.

Authors 5

C. Hansen (first)
F. Stickel (additional)
T. Berger (additional)
R. Richert (additional)
E. W. Fischer (additional)

References 55 Referenced 405

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:25 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 3:26 a.m.)
Indexed	1 day, 8 hours ago (Aug. 26, 2025, 2:31 a.m.)
Issued	28 years, 1 month ago (July 22, 1997)
Published	28 years, 1 month ago (July 22, 1997)
Published Print	28 years, 1 month ago (July 22, 1997)

Funders 0

None

BibTeX

@article{Hansen_1997, title={Dynamics of glass-forming liquids. III. Comparing the dielectric α- and β-relaxation of 1-propanol and o-terphenyl}, volume={107}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.474456}, DOI={10.1063/1.474456}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hansen, C. and Stickel, F. and Berger, T. and Richert, R. and Fischer, E. W.}, year={1997}, month=jul, pages={1086–1093} }

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  "abstract": "<jats:p>We have measured the dielectric relaxation of the glass-former 1-propanol for temperatures between 65 and 350 K in the frequency range 10\u22122 to 2\u22c51010\u2009Hz and the photon correlation spectro-scopy decays near Tg. Attributing the strong Debye-type process of 1-propanol to distinct -OH group effects leaves two faster processes related to the structural relaxation which can be identified as \u03b1-relaxation and Johari\u2013Goldstein type \u03b2-relaxation characteristic of nonhydrogen-bonding supercooled liquids. From the temperature dependent relaxation times \u03c4(T) regarding the three distinct loss peaks, we can specify an \u03b1-\u03b2-bifurcation temperature T\u03b2, which coincides with characteristic qualitative changes in the \u03c4(T) behavior, as also observed for ortho-terphenyl and other glass-forming liquids. This assignment is confirmed by the correla-tion times derived from incoherent quasielastic light-scattering data obtained from the simultaneously measured photon-correlation spectroscopy.</jats:p>",
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  "journal-issue": {
    "issue": "4",
    "published-print": {
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          22
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      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.474456",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
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        1997,
        7,
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  "published": {
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  }
}