Abstract
A structural investigation of liquid formamide was performed by neutron scattering at pressures of up to 4 kbar. We have also deduced the molecular pair correlation functions from x-ray studies at ambient pressure and in the 263–326 K temperature range. The spectra obtained are consistent with the presence of hydrogen-bonded open chains of molecules in the liquid state. The effect of both pressure and temperature on the hydrogen-bond network is examined.
References
21
Referenced
60
10.1063/1.455026
/ J. Chem. Phys. (1988)10.1107/S0365110X54001855
/ Acta Crystallogr. (1954)10.1107/S0567740878003519
/ Acta Crystallogr. B (1978)10.1021/j100369a015
/ J. Phys. Chem. (1990)10.1002/jrs.1250250207
/ J. Raman Spectrosc. (1994){'key': '2024020614324709200_r6', 'first-page': '3878', 'volume': '15', 'year': '1982', 'journal-title': 'J. Chem. Phys.'}
/ J. Chem. Phys. (1982)10.1016/0022-2860(79)80320-8
/ J. Mol. Struct. (1979){'key': '2024020614324709200_r8', 'first-page': '1059', 'volume': '5', 'year': '1994', 'journal-title': 'J. Electron. Spect. Relat. Phenom.'}
/ J. Electron. Spect. Relat. Phenom. (1994)10.1016/0022-2860(93)80183-V
/ J. Mol. Struct. (1993)10.1021/j100850a601
/ J. Phys. Chem. (1968)10.1515/zna-1983-0221
/ Z. Naturforsch. Teil A (1983)10.1080/00268978600100211
/ Mol. Phys. (1986)10.1246/bcsj.56.2116
/ Bull. Chem. Soc. Jpn. (1983)10.1039/f29858100277
/ J. Chem. Soc. Faraday Trans. (1985)10.1063/1.468555
/ J. Chem. Phys. (1995)10.1016/0021-9614(83)90160-X
/ J. Chem. Thermodynam. (1983)10.1088/0953-8984/3/22/016
/ J. Phys., Condens. Matter (1991){'key': '2024020614324709200_r18', 'first-page': '759', 'volume': '22', 'year': '1976', 'journal-title': 'Mol. Phys.'}
/ Mol. Phys. (1976)10.1063/1.438576
/ J. Chem. Phys. (1979){'key': '2024020614324709200_r20', 'first-page': '67', 'volume': '4', 'year': '1974', 'journal-title': 'Bull. Chem. Soc. Jpn.'}
/ Bull. Chem. Soc. Jpn. (1974){'key': '2024020614324709200_r21'}
Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 8:15 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 6, 2024, 9:51 a.m.) |
Indexed | 1 year, 6 months ago (Feb. 7, 2024, 1:50 a.m.) |
Issued | 28 years, 3 months ago (May 15, 1997) |
Published | 28 years, 3 months ago (May 15, 1997) |
Published Print | 28 years, 3 months ago (May 15, 1997) |
@article{Bellissent_Funel_1997, title={X-ray and neutron scattering studies of the temperature and pressure dependence of the structure of liquid formamide}, volume={106}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.473805}, DOI={10.1063/1.473805}, number={19}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bellissent-Funel, Marie-Claire and Nasr, Salah and Bosio, Louis}, year={1997}, month=may, pages={7913–7919} }