DOI: 10.1063/1.472979. Alignment of D2(<i>v</i>,<i> J</i>) desorbed from Cu(111): Low sensitivity of activated dissociative chemisorption to approach geometry

Alignment of D2(v, J) desorbed from Cu(111): Low sensitivity of activated dissociative chemisorption to approach geometry

10.1063/1.472979

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We have determined the alignment of D2(v,J) desorbed from Cu(111). The measurements reveal a small preference for ‘‘helicoptering’’ motion that increases with increasing J. At low J, the alignments are much smaller than predicted by recent calculations. We believe that the anisotropic potential may scramble the alignment as the molecules leave the surface.

Bibliography

Gulding, S. J., Wodtke, A. M., Hou, H., Rettner, C. T., Michelsen, H. A., & Auerbach, D. J. (1996). Alignment of D2(v,âJ) desorbed from Cu(111): Low sensitivity of activated dissociative chemisorption to approach geometry. The Journal of Chemical Physics, 105(21), 9702â9705.

Authors 6

S. J. Gulding (first)
A. M. Wodtke (additional)
H. Hou (additional)
C. T. Rettner (additional)
H. A. Michelsen (additional)
D. J. Auerbach (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:15 a.m.)
Deposited	1 year, 7 months ago (Feb. 5, 2024, 9:58 p.m.)
Indexed	3 months, 2 weeks ago (May 23, 2025, 1:25 p.m.)
Issued	28 years, 9 months ago (Dec. 1, 1996)
Published	28 years, 9 months ago (Dec. 1, 1996)
Published Print	28 years, 9 months ago (Dec. 1, 1996)

Funders 0

None

BibTeX

@article{Gulding_1996, title={Alignment of D2(v, J) desorbed from Cu(111): Low sensitivity of activated dissociative chemisorption to approach geometry}, volume={105}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.472979}, DOI={10.1063/1.472979}, number={21}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Gulding, S. J. and Wodtke, A. M. and Hou, H. and Rettner, C. T. and Michelsen, H. A. and Auerbach, D. J.}, year={1996}, month=dec, pages={9702–9705} }

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