DOI: 10.1063/1.472028. Observation of the second ordered phase of water on the MgO(100) surface: Low energy electron diffraction and helium atom scattering studies

Observation of the second ordered phase of water on the MgO(100) surface: Low energy electron diffraction and helium atom scattering studies

10.1063/1.472028

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The interaction of water with MgO (100) single crystal surfaces cleaved in situ has been studied by low energy electron diffraction and helium atom scattering in the temperature range 80 K–230 K. At Tcrystal=100–180 K water forms a layer with a c(4×2) symmetry in good agreement with previous spot profile analysis of low energy electron diffraction experiments. Adsorption at Tcrystal=185–221 K leads to the formation of a new ordered phase. The results of the low energy electron diffraction and elastic helium atom scattering experiments show that this high-temperature phase has a (3×2) symmetry, and that the unit cell contains a glide plane. The isosteric heat of adsorption at half coverage Qst=85.3 kJ/mol has been determined from equilibrium adsorption isotherms measured between 210 and 221 K.

Bibliography

Ferry, D., Glebov, A., Senz, V., Suzanne, J., Toennies, J. P., & Weiss, H. (1996). Observation of the second ordered phase of water on the MgO(100) surface: Low energy electron diffraction and helium atom scattering studies. The Journal of Chemical Physics, 105(4), 1697â1701.

Authors 6

D. Ferry (first)
A. Glebov (additional)
V. Senz (additional)
J. Suzanne (additional)
J. P. Toennies (additional)
H. Weiss (additional)

References 24 Referenced 101

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10.1016/0039-6028(92)90475-L / Surf. Sci. (1992)
10.1016/0039-6028(92)90476-M / Surf. Sci. (1992)
10.1016/0039-6028(93)90502-B / Surf. Sci. (1993)
10.1063/1.465187 / J. Chem. Phys. (1993)
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10.1016/0039-6028(92)90670-2 / Surf. Sci. (1992)
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10.1002/bbpc.199500080 / Ber. Bunsenges. Phys. Chem. (1995)
10.1016/0039-6028(93)90721-U / Surf. Sci. (1993)
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{'key': '2024020612394725000_r14'}
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{'key': '2024020612394725000_r16'}
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{'key': '2024020612394725000_r20'}
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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:15 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 8:17 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 7:59 a.m.)
Issued	29 years ago (July 22, 1996)
Published	29 years ago (July 22, 1996)
Published Print	29 years ago (July 22, 1996)

Funders 0

None

BibTeX

@article{Ferry_1996, title={Observation of the second ordered phase of water on the MgO(100) surface: Low energy electron diffraction and helium atom scattering studies}, volume={105}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.472028}, DOI={10.1063/1.472028}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ferry, D. and Glebov, A. and Senz, V. and Suzanne, J. and Toennies, J. P. and Weiss, H.}, year={1996}, month=jul, pages={1697–1701} }

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