DOI: 10.1063/1.471121. Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non-Markovian molecular reorientation

Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non-Markovian molecular reorientation

10.1063/1.471121

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A simple model of non-Markovian molecular reorientation is applied to multidimensional NMR experiments in supercooled liquids and polymers close to the glass transition. The process of exchange between components of a correlation time distribution is related with the notions ‘‘exponential/nonexponential, homogeneous/heterogeneous, Markovian/non-Markovian, and ergodic/nonergodic’’ often used in relation with molecular dynamics in viscous systems. By working out a detailed example of two-state exchange the difference between 2D and reduced 4D-spectra with respect to the mechanism and dynamics of molecular reorientation in complex liquids is elucidated.

Bibliography

Sillescu, H. (1996). Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non-Markovian molecular reorientation. The Journal of Chemical Physics, 104(13), 4877â4886.

Authors 1

Hans Sillescu (first)

References 34 Referenced 45

10.1103/PhysRevLett.66.3020 / Phys. Rev. Lett. (1991)
10.1103/PhysRevLett.75.2851 / Phys. Rev. Lett. (1995)
{'key': '2024020706372252300_r3'}
{'key': '2024020706372252300_r4', 'first-page': '262', 'volume': '16', 'year': '1965', 'journal-title': 'Ann. Phys. (Leipzig)'} / Ann. Phys. (Leipzig) (1965)
10.1063/1.1675142 / J. Chem. Phys. (1971)
{'key': '2024020706372252300_r6'}
{'key': '2024020706372252300_r7'}
10.1063/1.1712250 / J. Chem. Phys. (1967)
10.1016/0001-8716(72)80028-2 / Adv. Mol. Relaxation Processes (1972)
{'key': '2024020706372252300_r10'}
{'key': '2024020706372252300_r11'}
{'key': '2024020706372252300_r12'}
{'key': '2024020706372252300_r13'}
{'key': '2024020706372252300_r14'}
10.1007/BF01323572 / Z. Phys. B (1992)
{'key': '2024020706372252300_r16', 'first-page': '248', 'volume': '172–174', 'year': '1994', 'journal-title': 'J. Non-Cryst. Solids'} / J. Non-Cryst. Solids (1994)
10.1002/actp.1994.010450304 / Acta Polym. (1994)
{'key': '2024020706372252300_r18'}
{'key': '2024020706372252300_r19'}
{'key': '2024020706372252300_r20'}
{'key': '2024020706372252300_r21'}
10.1063/1.470551 / J. Chem. Phys. (1995)
10.1016/0009-2614(90)85047-G / Chem. Phys. Lett. (1990)
10.1063/1.470902 / J. Chem. Phys. (1996)
{'key': '2024020706372252300_r25'}
{'key': '2024020706372252300_r26', 'first-page': '233', 'volume': '131–133', 'year': '1991', 'journal-title': 'J. Non-Cryst. Solids'} / J. Non-Cryst. Solids (1991)
{'key': '2024020706372252300_r27', 'first-page': '523', 'volume': '191', 'year': '1993', 'journal-title': 'Physica A'} / Physica A (1993)
10.1103/PhysRevLett.50.77 / Phys. Rev. Lett. (1983)
10.1126/science.231.4740.814 / Science (1986)
{'key': '2024020706372252300_r30'}
{'key': '2024020706372252300_r31'}
10.1063/1.455174 / J. Chem. Phys. (1988)
{'key': '2024020706372252300_r33'}
{'key': '2024020706372252300_r34'}

Dates

Type	When
Created	23 years ago (July 26, 2002, 8:34 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 5:59 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 1:06 a.m.)
Issued	29 years, 4 months ago (April 1, 1996)
Published	29 years, 4 months ago (April 1, 1996)
Published Print	29 years, 4 months ago (April 1, 1996)

Funders 0

None

BibTeX

@article{Sillescu_1996, title={Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non-Markovian molecular reorientation}, volume={104}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.471121}, DOI={10.1063/1.471121}, number={13}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sillescu, Hans}, year={1996}, month=apr, pages={4877–4886} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        11
      ]
    ],
    "date-time": "2024-02-11T06:06:20Z",
    "timestamp": 1707631580092
  },
  "reference-count": 34,
  "publisher": "AIP Publishing",
  "issue": "13",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1996,
        4,
        1
      ]
    ]
  },
  "abstract": "<jats:p>A simple model of non-Markovian molecular reorientation is applied to multidimensional NMR experiments in supercooled liquids and polymers close to the glass transition. The process of exchange between components of a correlation time distribution is related with the notions \u2018\u2018exponential/nonexponential, homogeneous/heterogeneous, Markovian/non-Markovian, and ergodic/nonergodic\u2019\u2019 often used in relation with molecular dynamics in viscous systems. By working out a detailed example of two-state exchange the difference between 2D and reduced 4D-spectra with respect to the mechanism and dynamics of molecular reorientation in complex liquids is elucidated.</jats:p>",
  "DOI": "10.1063/1.471121",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T12:34:49Z",
    "timestamp": 1027686889000
  },
  "page": "4877-4886",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 45,
  "title": "Multidimensional nuclear magnetic resonance in complex liquids analyzed by a simple model for non-Markovian molecular reorientation",
  "prefix": "10.1063",
  "volume": "104",
  "author": [
    {
      "given": "Hans",
      "family": "Sillescu",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Institut f\u00fcr Physikalische Chemie, Universit\u00e4t Mainz, Jakob-Welder-Weg 15, D-55099 Mainz, Germany"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024020706372252300_r1",
      "doi-asserted-by": "crossref",
      "first-page": "3020",
      "DOI": "10.1103/PhysRevLett.66.3020",
      "volume": "66",
      "year": "1991",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020706372252300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "2851",
      "DOI": "10.1103/PhysRevLett.75.2851",
      "volume": "75",
      "year": "1995",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020706372252300_r3"
    },
    {
      "key": "2024020706372252300_r4",
      "first-page": "262",
      "volume": "16",
      "year": "1965",
      "journal-title": "Ann. Phys. (Leipzig)"
    },
    {
      "key": "2024020706372252300_r5",
      "doi-asserted-by": "crossref",
      "first-page": "2110",
      "DOI": "10.1063/1.1675142",
      "volume": "54",
      "year": "1971",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020706372252300_r6"
    },
    {
      "key": "2024020706372252300_r7"
    },
    {
      "key": "2024020706372252300_r8",
      "doi-asserted-by": "crossref",
      "first-page": "2178",
      "DOI": "10.1063/1.1712250",
      "volume": "47",
      "year": "1967",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020706372252300_r9",
      "doi-asserted-by": "crossref",
      "first-page": "91",
      "DOI": "10.1016/0001-8716(72)80028-2",
      "volume": "3",
      "year": "1972",
      "journal-title": "Adv. Mol. Relaxation Processes"
    },
    {
      "key": "2024020706372252300_r10"
    },
    {
      "key": "2024020706372252300_r11"
    },
    {
      "key": "2024020706372252300_r12"
    },
    {
      "key": "2024020706372252300_r13"
    },
    {
      "key": "2024020706372252300_r14"
    },
    {
      "key": "2024020706372252300_r15",
      "doi-asserted-by": "crossref",
      "first-page": "195",
      "DOI": "10.1007/BF01323572",
      "volume": "88",
      "year": "1992",
      "journal-title": "Z. Phys. B"
    },
    {
      "key": "2024020706372252300_r16",
      "first-page": "248",
      "volume": "172\u2013174",
      "year": "1994",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024020706372252300_r17",
      "doi-asserted-by": "crossref",
      "first-page": "148",
      "DOI": "10.1002/actp.1994.010450304",
      "volume": "45",
      "year": "1994",
      "journal-title": "Acta Polym."
    },
    {
      "key": "2024020706372252300_r18"
    },
    {
      "key": "2024020706372252300_r19"
    },
    {
      "key": "2024020706372252300_r20"
    },
    {
      "key": "2024020706372252300_r21"
    },
    {
      "key": "2024020706372252300_r22",
      "doi-asserted-by": "crossref",
      "first-page": "5684",
      "DOI": "10.1063/1.470551",
      "volume": "103",
      "year": "1995",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020706372252300_r23",
      "doi-asserted-by": "crossref",
      "first-page": "381",
      "DOI": "10.1016/0009-2614(90)85047-G",
      "volume": "166",
      "year": "1990",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024020706372252300_r24",
      "doi-asserted-by": "crossref",
      "first-page": "314",
      "DOI": "10.1063/1.470902",
      "volume": "104",
      "year": "1996",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020706372252300_r25"
    },
    {
      "key": "2024020706372252300_r26",
      "first-page": "233",
      "volume": "131\u2013133",
      "year": "1991",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "2024020706372252300_r27",
      "first-page": "523",
      "volume": "191",
      "year": "1993",
      "journal-title": "Physica A"
    },
    {
      "key": "2024020706372252300_r28",
      "doi-asserted-by": "crossref",
      "first-page": "77",
      "DOI": "10.1103/PhysRevLett.50.77",
      "volume": "50",
      "year": "1983",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024020706372252300_r29",
      "doi-asserted-by": "crossref",
      "first-page": "814",
      "DOI": "10.1126/science.231.4740.814",
      "volume": "231",
      "year": "1986",
      "journal-title": "Science"
    },
    {
      "key": "2024020706372252300_r30"
    },
    {
      "key": "2024020706372252300_r31"
    },
    {
      "key": "2024020706372252300_r32",
      "doi-asserted-by": "crossref",
      "first-page": "1234",
      "DOI": "10.1063/1.455174",
      "volume": "89",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024020706372252300_r33"
    },
    {
      "key": "2024020706372252300_r34"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/104/13/4877/19288938/4877_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/104/13/4877/19288938/4877_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        7
      ]
    ],
    "date-time": "2024-02-07T10:59:51Z",
    "timestamp": 1707303591000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/104/13/4877/480051/Multidimensional-nuclear-magnetic-resonance-in"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1996,
        4,
        1
      ]
    ]
  },
  "references-count": 34,
  "journal-issue": {
    "issue": "13",
    "published-print": {
      "date-parts": [
        [
          1996,
          4,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.471121",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1996,
        4,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1996,
        4,
        1
      ]
    ]
  }
}