DOI: 10.1063/1.470260. Immiscibility of large and small symmetric diblock copolymers

Immiscibility of large and small symmetric diblock copolymers

10.1063/1.470260

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We examine binary mixtures of large and small symmetric AB diblock copolymers using self-consistent field theory. In accord with experiment, we find that when the ratio of their polymerization indexes exceeds about 1:5, they become immiscible producing a coexistence between long- and short-period lamellar phases. As in experiment, the short-period phase contains few large diblocks, but the long-period one contains a substantial volume fraction of small diblocks.

Bibliography

Matsen, M. W. (1995). Immiscibility of large and small symmetric diblock copolymers. The Journal of Chemical Physics, 103(8), 3268â3271.

Authors 1

M. W. Matsen (first)

References 20 Referenced 77

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10.1021/ma00063a039 / Macromolecules (1993)
10.1021/ma00084a043 / Macromolecules (1994)
10.1021/ma00093a044 / Macromolecules (1994)
10.1021/ma00100a020 / Macromolecules (1994)
10.1016/0032-3861(91)90235-B / Polymer (1991)
10.1063/1.430517 / J. Chem. Phys. (1975)
10.1103/PhysRevLett.74.4225 / Phys. Rev. Lett. (1995)
{'key': '2024021110402873600_r8a'}
{'key': '2024021110402873600_r9', 'first-page': '733', 'volume': '61', 'year': '1985', 'journal-title': 'Sov. Phys. JETP'} / Sov. Phys. JETP (1985)
10.1016/0032-3861(90)90094-F / Polymer (1990)
10.1021/ma00192a057 / Macromolecules (1989)
{'key': '2024021110402873600_r12'}
{'key': '2024021110402873600_r13'}
10.1021/ma00193a040 / Macromolecules (1989)
10.1021/ma00221a023 / Macromolecules (1990)
10.1021/ma00234a017 / Macromolecules (1982)
10.1021/ma00089a008 / Macromolecules (1994)
10.1021/ma00103a030 / Macromolecules (1994)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:36 a.m.)
Deposited	1 year, 6 months ago (Feb. 11, 2024, 5:40 a.m.)
Indexed	5 days, 17 hours ago (Aug. 22, 2025, 12:45 a.m.)
Issued	30 years ago (Aug. 22, 1995)
Published	30 years ago (Aug. 22, 1995)
Published Print	30 years ago (Aug. 22, 1995)

Funders 0

None

BibTeX

@article{Matsen_1995, title={Immiscibility of large and small symmetric diblock copolymers}, volume={103}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.470260}, DOI={10.1063/1.470260}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Matsen, M. W.}, year={1995}, month=aug, pages={3268–3271} }

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