DOI: 10.1063/1.470045. Nucleation in molecular and dipolar fluids: Interaction site model

Nucleation in molecular and dipolar fluids: Interaction site model

10.1063/1.470045

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We consider the effect of molecular anisotropy and dipole moment on the rate of homogeneous and heterogeneous nucleation of molecular and dipolar fluids. Density functional theory is applied to an interaction site model of molecules composed of two tangent or fused hard spheres interacting through Lennard-Jones and coulombic potentials. Interfacial properties are conditioned by entropy vs energy competition. For nucleation on a charged hard sphere, the calculated rates depend strongly on the size and charge of the central seed. Preferred surface orientations of the dipolar molecules are responsible for nucleation rates differing by several orders of magnitude for charges of different sign.

Bibliography

Talanquer, V., & Oxtoby, D. W. (1995). Nucleation in molecular and dipolar fluids: Interaction site model. The Journal of Chemical Physics, 103(9), 3686â3695.

Authors 2

V. Talanquer (first)
David W. Oxtoby (additional)

References 36 Referenced 50

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:34 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 9:15 a.m.)
Indexed	11 months, 1 week ago (Sept. 13, 2024, 7:17 a.m.)
Issued	29 years, 11 months ago (Sept. 1, 1995)
Published	29 years, 11 months ago (Sept. 1, 1995)
Published Print	29 years, 11 months ago (Sept. 1, 1995)

Funders 0

None

BibTeX

@article{Talanquer_1995, title={Nucleation in molecular and dipolar fluids: Interaction site model}, volume={103}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.470045}, DOI={10.1063/1.470045}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Talanquer, V. and Oxtoby, David W.}, year={1995}, month=sep, pages={3686–3695} }

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