DOI: 10.1063/1.467782. Monte Carlo simulation of the glass transition in two- and three-dimensional polymer melts: Influence of the spatial dimension

Monte Carlo simulation of the glass transition in two- and three-dimensional polymer melts: Influence of the spatial dimension

10.1063/1.467782

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

This Monte Carlo simulation was undertaken to provide some qualitative insight into the dependence of the glass transition of polymer melts on the spatial dimension. To this end, two- and three-dimensional systems were simulated, in which we kept the external conditions, such as the density or the cooling schedule, the same for both dimensions. The melts, simulated by a lattice model (bond-fluctuation model), undergo a kinetic freezing, while being continuously cooled from the equilibrium liquid to the nonequilibrium glassy phase. The resulting glass transition as well as the other simulation results indicate that the spatial constraints are stronger in three than in two dimensions. This finding is reminiscent of the influence of the spatial dimension on the ability of a liquid to crystallize.

Bibliography

Lobe, B., & Baschnagel, J. (1994). Monte Carlo simulation of the glass transition in two- and three-dimensional polymer melts: Influence of the spatial dimension. The Journal of Chemical Physics, 101(2), 1616â1624.

Authors 2

B. Lobe (first)
J. Baschnagel (additional)

References 53 Referenced 13

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 11, 2024, 12:25 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 12:40 a.m.)
Issued	31 years, 1 month ago (July 15, 1994)
Published	31 years, 1 month ago (July 15, 1994)
Published Print	31 years, 1 month ago (July 15, 1994)

Funders 0

None

BibTeX

@article{Lobe_1994, title={Monte Carlo simulation of the glass transition in two- and three-dimensional polymer melts: Influence of the spatial dimension}, volume={101}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.467782}, DOI={10.1063/1.467782}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lobe, B. and Baschnagel, J.}, year={1994}, month=jul, pages={1616–1624} }

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