DOI: 10.1063/1.467570. Lattice-gas model mimicking the NO+CO reaction on Pt(100)

Lattice-gas model mimicking the NO+CO reaction on Pt(100)

10.1063/1.467570

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Various NO-reduction reactions on Pt(100) exhibit similar dynamical behavior, presumably due to an empty site requirement for NO dissociation. This motivates analysis of a lattice-gas model which incorporates this feature, and which here is chosen to mimic the NO+CO reaction on Pt(100): both reactants adsorb at single empty sites, NO instantaneously dissociates given an adjacent empty site (and nitrogen adatoms thus formed are immediately removed), and adjacent CO and O instantaneously react. We also include desorption of adsorbed NO and CO, but no adspecies diffusion. At lower temperatures where desorption is absent, we show that poisoning occurs with the reaction rate decreasing as RCO2∼ e−kt, where k≳0 except for equal reactant adsorption rates. The introduction of desorption produces reactive steady states, and (in different regimes) nonequilibrium poisoning transitions, critical points, and transitions to bistability.

Bibliography

Meng, B., Weinberg, W. H., & Evans, J. W. (1994). Lattice-gas model mimicking the NO+CO reaction on Pt(100). The Journal of Chemical Physics, 101(4), 3234â3242.

Authors 3

Baoqi Meng (first)
W. Henry Weinberg (additional)
J. W. Evans (additional)

References 52 Referenced 31

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 12:43 p.m.)
Indexed	1 year, 6 months ago (Feb. 7, 2024, 1:10 p.m.)
Issued	31 years ago (Aug. 15, 1994)
Published	31 years ago (Aug. 15, 1994)
Published Print	31 years ago (Aug. 15, 1994)

Funders 0

None

BibTeX

@article{Meng_1994, title={Lattice-gas model mimicking the NO+CO reaction on Pt(100)}, volume={101}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.467570}, DOI={10.1063/1.467570}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Meng, Baoqi and Weinberg, W. Henry and Evans, J. W.}, year={1994}, month=aug, pages={3234–3242} }

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    ]
  },
  "references-count": 52,
  "journal-issue": {
    "issue": "4",
    "published-print": {
      "date-parts": [
        [
          1994,
          8,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.467570",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1994,
        8,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1994,
        8,
        15
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    ]
  }
}