DOI: 10.1063/1.467441. Ultrafast infrared pump–probe spectroscopy of water: A theoretical description

Ultrafast infrared pump–probe spectroscopy of water: A theoretical description

10.1063/1.467441

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory is developed to describe a recent infrared pump–probe experiment in water. This theory is a statistical theory, similar to those elaborated earlier to interpret ultraviolet and visible spectra. Nonlinear optical processes involved are analyzed in terms of four-time correlation functions of the electric dipole moment of the system and of the incident electric fields, respectively. An analytical expression for the transient infrared signal is presented. The observed spectral characteristics are attributed to a gradual thermalization of the initial, pump-prepared state. The substructure of the observed bands is interpreted. This experiment probes the kinetics of conversion of H-bonds of different lengths into each other.

Bibliography

Bratos, S., & Leicknam, J.-Cl. (1994). Ultrafast infrared pumpâprobe spectroscopy of water: A theoretical description. The Journal of Chemical Physics, 101(6), 4536â4546.

Authors 2

S. Bratos (first)
J-Cl. Leicknam (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:02 a.m.)
Deposited	1 year, 6 months ago (Feb. 6, 2024, 1:52 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 8:02 a.m.)
Issued	30 years, 11 months ago (Sept. 15, 1994)
Published	30 years, 11 months ago (Sept. 15, 1994)
Published Print	30 years, 11 months ago (Sept. 15, 1994)

Funders 0

None

BibTeX

@article{Bratos_1994, title={Ultrafast infrared pump–probe spectroscopy of water: A theoretical description}, volume={101}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.467441}, DOI={10.1063/1.467441}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bratos, S. and Leicknam, J-Cl.}, year={1994}, month=sep, pages={4536–4546} }

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