DOI: 10.1063/1.465327. The molecular parameters of the antimony monodeuteride radical from diode laser spectroscopy

The molecular parameters of the antimony monodeuteride radical from diode laser spectroscopy

10.1063/1.465327

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Extensive measurements of the 3Σ ground state infrared spectrum of the antimony monodeuteride radical (SbD) have been carried out using a diode laser spectrometer. Transitions of the fundamental band of all three components of two isotopomers of SbD were measured with a nominal accuracy of ±0.001 cm−1. Only transitions of the O+ component of the v=1←2 hotband were intense enough to be observed. The entire data set was fitted as a single 3Σ state and accurate molecular parameters determined. The LMR data of Stackmann et al. [Mol. Phys. (in press)] on SbH provided invaluable aid with the assignment. Measurements were also carried out on two isotopomers of SbH in order to improve the molecular parameters available for these species.

Bibliography

Urban, R.-D., Essig, K., & Jones, H. (1993). The molecular parameters of the antimony monodeuteride radical from diode laser spectroscopy. The Journal of Chemical Physics, 99(3), 1591â1596.

Authors 3

Rolf-Dieter Urban (first)
Kay Essig (additional)
Harold Jones (additional)

References 15 Referenced 15

{'key': '2024021022473575700_r1'}
{'key': '2024021022473575700_r2'}
10.1007/BF01397124 / Z. Phys. (1927)
10.1016/0009-2614(91)90385-M / Chem. Phys. Lett. (1991)
10.1088/0031-8949/10/6/008 / Phys. Scr. (1974)
10.1088/0031-8949/24/3/008 / Phys. Scr. (1981)
{'key': '2024021022473575700_r7'}
{'key': '2024021022473575700_r8'}
10.1063/1.458484 / J. Chem. Phys. (1990)
10.1016/0009-2614(89)80007-7 / Chem. Phys. Lett. (1989)
{'key': '2024021022473575700_r11', 'first-page': '100709', 'year': '1988', 'journal-title': 'NASA Technical Memorandum'} / NASA Technical Memorandum (1988)
{'key': '2024021022473575700_r12'}
{'key': '2024021022473575700_r13'}
10.1103/PhysRev.41.721 / Phys. Rev. (1932)
{'key': '2024021022473575700_r15'}

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:28 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 5:47 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:10 p.m.)
Issued	32 years, 1 month ago (Aug. 1, 1993)
Published	32 years, 1 month ago (Aug. 1, 1993)
Published Print	32 years, 1 month ago (Aug. 1, 1993)

Funders 0

None

BibTeX

@article{Urban_1993, title={The molecular parameters of the antimony monodeuteride radical from diode laser spectroscopy}, volume={99}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.465327}, DOI={10.1063/1.465327}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Urban, Rolf-Dieter and Essig, Kay and Jones, Harold}, year={1993}, month=aug, pages={1591–1596} }

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