DOI: 10.1063/1.464161. Temperature dependence of the reaction of nickel clusters with deuterium

Temperature dependence of the reaction of nickel clusters with deuterium

10.1063/1.464161

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The kinetics of reactions of D2 with Ni9 through Ni14 are studied in a flow-tube reactor over the temperature range 133–413 K. Rate constants for the dissociative chemisorption of the first D2 molecule have been determined. Reaction probabilities are near unity for Ni10–Ni14 and are essentially independent of temperature. For Ni9, the reaction probability is about 5% between 213 and 413 K, but increases below 213 K to ∼50% at 133 K. The possibility that these reactions are mediated by a physisorbed precursor state is discussed. The increase in Ni9 reactivity below 213 K is interpreted as due to an increase in the initial trapping of the D2 molecule on the cluster’s surface.

Bibliography

Zhu, L., Ho, J., Parks, E. K., & Riley, S. J. (1993). Temperature dependence of the reaction of nickel clusters with deuterium. The Journal of Chemical Physics, 98(4), 2798â2804.

Authors 4

L. Zhu (first)
J. Ho (additional)
E. K. Parks (additional)
S. J. Riley (additional)

References 22 Referenced 33

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:22 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 10:38 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:59 a.m.)
Issued	32 years, 6 months ago (Feb. 15, 1993)
Published	32 years, 6 months ago (Feb. 15, 1993)
Published Print	32 years, 6 months ago (Feb. 15, 1993)

Funders 0

None

BibTeX

@article{Zhu_1993, title={Temperature dependence of the reaction of nickel clusters with deuterium}, volume={98}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.464161}, DOI={10.1063/1.464161}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Zhu, L. and Ho, J. and Parks, E. K. and Riley, S. J.}, year={1993}, month=feb, pages={2798–2804} }

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