Abstract
Expressions for the frequency and intensity of the fundamental-vibrational transitions of a polyatomic molecule in the presence of a uniform or nonuniform electric field are reported. They have been developed on the basis of perturbation theory and take into account, individually, first-order electrical and mechanical anharmonicity. They are more general than previously-used expressions, since terms which are quadratic in the field strength are included. As an example of their use and of their interpretative capability, they are applied to CO.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 8:22 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 10:48 p.m.) |
Indexed | 3 days, 9 hours ago (Aug. 27, 2025, 12:38 p.m.) |
Issued | 32 years, 6 months ago (Feb. 15, 1993) |
Published | 32 years, 6 months ago (Feb. 15, 1993) |
Published Print | 32 years, 6 months ago (Feb. 15, 1993) |
@article{Bishop_1993, title={The vibrational Stark effect}, volume={98}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.464090}, DOI={10.1063/1.464090}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bishop, David M.}, year={1993}, month=feb, pages={3179–3184} }